Crystal structure of cis-bis (N,N-dimethyl_N'-benzoylthioureato) palladium (II)

Abstract

In this study cis-bis(N,N-dimethyl-N'-benzoylthioureato) palladium(II) is synthesised and the crystal structure is determined by X-ray diffraction methods. It crystallises in the space group P21/c, with a = 11.943(1) Å, b = 11.713(1) Å, c = 15.345(1) Å, $beta$ = 93.90(1)°, and $D_{calc}$ = 1.616 g$cm^{-1}$ for Z = 4. The Pd(II) atom is in a four-coordinate geometry consisting of two thiocarbonyl S and two carbonyl O atoms from two ligand groups. The Pd-S and Pd-O bond lengths are 2.2313(6) and 2.0211(16) Å, respectively.