Journals / Turkish Journal of Chemistry / 2015 / Cilt: 39 - Sayı: 6
The synthesis, characterization, and catalytic properties of (2-C,N) palladacycles with N-heterocyclic carbene-based ancillary ligands
- Journal
- Turkish Journal of Chemistry
- Pages
- 1310–1316
- DOI
- —
Abstract
Novel ve-membered (K2-C,N)-palladacyclic complexes were prepared from the reaction of the corresponding acetate-bridged palladacycle dimer with N-heterocyclic carbene (NHC) ligands in high yields. Palladacyclic complexes ( 3 ) were fully characterized by elemental analysis and 1 H and 13 C NMR spectroscopy. Palladacyclic complexes were tested as catalyst for the C{C bond forming reaction. These complexes were found to be efficient catalysts for the Suzuki{Miyaura reaction of aryl bromides.