Green Preparation of Hyphaene thebaica Fiber Grafted Acrylic Acid for Adsorption of Pb(II) ions from Aqueous Solution

Abstract

In this study, a green chemistry approach was employed in the preparation of Hyphaene thebaicafiber grafted polyacrylic acid via microwave assisted method using potassium persulfate as the chemicalinitiator. The optimum percentage grafting of 92% was achieved under 5 g concentration of acrylic acid,0.2 g concentration of potassium persulfate (KPS) and 2 minutes of reaction time. The grafted sample wascharacterized using the following techniques, FTIR, SEM and XRD. The prepared graft copolymer wasexamined for adsorption of Pb(II) ions from aqueous solution in batch mode systems. The adsorptionparameters such as pH, initial metal ion concentration and contact time were also studied. The Langmuirand Freundlich isotherm models were applied to simulate the equilibrium adsorption experimental data.The Langmuir model fitted well with experimental data with maximum adsorption capacity (qmax) of 20.37mg/g at 45 minutes. Higher regression coefficient obtained confirmed the suitability of the Langmuirisotherm model which assumed monolayer coverage on the adsorbent surface. The adsorption studiesrevealed the efficacy of the grafted fiber for removal of Pb(II) ions from dilute aqueous solutions.