Journals / Turkish Journal of Chemistry / 2002 / Cilt: 26 - Sayı: 5
Bifunctional Allyl-Sulphonium Salt as a Novel Addition--Fragmentation Agent for Photoinitiated Cationic Polymerization
- Journal
- Turkish Journal of Chemistry
- Pages
- 793–800
- DOI
- —
Abstract
Bifunctional allyl tetrahydrothiophenium hexafluoroantimonate was synthesized via a one-pot reaction of 3-chloro-2-chloromethylpropene with thiophene in the presence of sodium hexafluoroantimonate. The initiation capability of this salt, in conjunction with a photochemical free radical source such as 2,2-dimethoxy-2-phenyl acetophenone and benzophenone, via an addition-fragmentation mechanism in the cationic polymerization of cyclohexene oxide and butyl vinyl ether is investigated.
Özet
Bifunctional allyl tetrahydrothiophenium hexafluoroantimonate was synthesized via a one-pot reaction of 3-chloro-2-chloromethylpropene with thiophene in the presence of sodium hexafluoroantimonate. The initiation capability of this salt, in conjunction with a photochemical free radical source such as 2,2-dimethoxy-2-phenyl acetophenone and benzophenone, via an addition-fragmentation mechanism in the cationic polymerization of cyclohexene oxide and butyl vinyl ether is investigated.