Journals / Turkish Journal of Chemistry / 2005 / Cilt: 29 - Sayı: 2
Synthesis and Structural Characterization of the 2-[(o-pyridyl)-sulfanylmethyl]-pyrimidine-silver(I) Complex [Ag2(opsp)2](NO3)2
- Journal
- Turkish Journal of Chemistry
- Pages
- 193–197
- DOI
- —
Abstract
The new silver(I) complexe [Ag2(opsp)2](NO3)2 (1) was synthesized by the self-assembly of AgX (X = NO3-) with the versatile multidentate ligand opsp (opsp = 2-[(o-pyridyl)-sulfanylmethyl]- pyrimidine). X-ray single-crystal diffraction analyses show that 1 is dinuclear molecule. In 1, 1 opsp ligand acts in a bidentate mode with 2 nitrogen atoms from a pyridine ring and a pyrimidine ring coordinating to 2 Ag(I) atoms, and the Ag(I) center is 2-coordinated by 2 nitrogen atoms showing linear coordination geometry.
Özet
The new silver(I) complexe [Ag2(opsp)2](NO3)2 (1) was synthesized by the self-assembly of AgX (X = NO3-) with the versatile multidentate ligand opsp (opsp = 2-[(o-pyridyl)-sulfanylmethyl]- pyrimidine). X-ray single-crystal diffraction analyses show that 1 is dinuclear molecule. In 1, 1 opsp ligand acts in a bidentate mode with 2 nitrogen atoms from a pyridine ring and a pyrimidine ring coordinating to 2 Ag(I) atoms, and the Ag(I) center is 2-coordinated by 2 nitrogen atoms showing linear coordination geometry.