Assessing PM2.5 concentrations in Tehran, Iran, from space using MAIAC, deep blue, and dark target AOD and machine learning algorithms

Özet

This study aims to explore the spatial estimation of fine particulate matter (PM2.5) using 10-km merged darktarget and deep blue (DB_DT) Aerosol Optical Depth (AOD) and 1-km Multi-Angle Implementation ofAtmospheric Correction (MAIAC) AOD over Tehran. The ability of four Machine Learning Algorithms (MLAs) topredict PM2.5 concentrations is also investigated. Results show that the association of satellite AOD with surfacePM significantly increases after considering the contribution of relative humidity in PM mass concentration andnormalization of AOD to Planetary boundary layer height (PBLH). The examination of derived aerosol layerheight (ALH) from 159 Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) profilesshows that PBLH could successfully represent the top of aerosol-laden layers. Surprisingly, the highest correlationwas found between normalized 10-km DB_DT AOD and corrected PM2.5 measurements. Consequently,random forest (RF) fed by this AOD product has yielded the best performance (R2=0.68, RMSE=17.52 andMRE=27.46%). Importance analysis of variables reveals that DB_DT and meteorological fields are of highestand least importance among selected variables, respectively. The RF performance is less satisfactory duringsummer which is assumed to be caused by the omission of unknown features representing the formation ofsecondary aerosols. The inferior accuracy of estimation in the north and east of Tehran is also linked to lackingfeatures which could feed the transportation of PM2.5 from west to the east of the study area into MLAs.