Selective Oxidation of Thiols to Disulfides Catalyzed by Iron(III) -- Tetra Phenyl Porphyrin Using Urea-Hydrogen Peroxide as Oxidizing Reagent

Bahador KARAMI,Morteza MONTAZEROZOHORI,Majid MOGHADAM,Mohammad Hosein HABIBI,Khodabakhsh NIKNAM

Journal: Turkish Journal of Chemistry
Issue: 2005 · Cilt: 29 - Sayı: 5
Pages: 539–546
DOI: —

Abstract

Oxidation of thiols to disulfides catalyzed by iron(III) -- tetra phenyl prophyrin Fe (TPP)Cl was investigated using urea-hydrogen peroxide adduct (UHP) as an oxidant in methanol as a solvent.

Özet

Oxidation of thiols to disulfides catalyzed by iron(III) -- tetra phenyl prophyrin Fe (TPP)Cl was investigated using urea-hydrogen peroxide adduct (UHP) as an oxidant in methanol as a solvent.

Keywords: Thiols, Fe (TPP) Cl, Urea hydrogen peroxide, disulfides