Journals / Turkish Journal of Chemistry / 2011 / Cilt: 35 - Sayı: 3
Tridentate ligands derived from L-tert-Leucine for the Cu(II) mediated asymmetric Henry reaction
- Journal
- Turkish Journal of Chemistry
- Pages
- 361–374
- DOI
- —
Abstract
Chiral tridentate Schiff base ligands were prepared from L-tert-Leucine and used as catalysts in the asymmetric Henry reaction in the presence of Cu(II) ions. Moderate enantiomeric excesses (up to 66%) and yields (up to 76%) of the desired b-nitroalcohols were obtained.
Özet
Chiral tridentate Schiff base ligands were prepared from L-tert-Leucine and used as catalysts in the asymmetric Henry reaction in the presence of Cu(II) ions. Moderate enantiomeric excesses (up to 66%) and yields (up to 76%) of the desired b-nitroalcohols were obtained.