Journals / Turkish Journal of Chemistry / 2010 / Cilt: 34 - Sayı: 4

Silica supported polyphosphoric acid (PPA-SiO2): an efficient and reusable heterogeneous catalyst for the one-pot synthesis of a -amino phosphonates

Pages
565–570
DOI
—

Abstract

An efficient green protocol is described for the preparation of a -amino phosphonates, employing a one-pot three-component condensation reaction between aldehydes, amines, and trialkyl phosphites in the presence of PPA-SiO2 under solvent-free conditions at 80 °C. The present procedure offer advantages such as high to excellent yields, short reaction time, inexpensiveness, recovery, and reusability of catalyst.

Özet

An efficient green protocol is described for the preparation of a -amino phosphonates, employing a one-pot three-component condensation reaction between aldehydes, amines, and trialkyl phosphites in the presence of PPA-SiO2 under solvent-free conditions at 80 °C. The present procedure offer advantages such as high to excellent yields, short reaction time, inexpensiveness, recovery, and reusability of catalyst.

Keywords: a -Amino phosphonates; PPA-SiO2; heterogeneous catalyst; trialkyl phosphites