Journals / Turkish Journal of Chemistry / 2006 / Cilt: 30 - Sayı: 4
The Synthesis of 4-Phenoxyphenylglyoxime and 4,4 -Oxybis(phenylglyoxime) and Their Complexes with Cu(II), Ni(II) and Co(II)
- Journal
- Turkish Journal of Chemistry
- Pages
- 461–469
- DOI
- —
Abstract
4-Acetyldiphenyl ether and 4,4'-diacetyldiphenyl ether were synthesized from diphenyl ether and acetyl chloride in the presence of AlCl3 used as catalyst. Subsequently, their keto oxime and glyoxime derivatives were prepared. The metal complexes of the glyoximes such as Cu(II), Ni(II) and Co(II) were also prepared. The structures of these ligands and their complexes were identified by FT-IR, 1H NMR and 13C NMR spectral data, elemental analysis and magnetic measurements.
Özet
4-Acetyldiphenyl ether and 4,4'-diacetyldiphenyl ether were synthesized from diphenyl ether and acetyl chloride in the presence of AlCl3 used as catalyst. Subsequently, their keto oxime and glyoxime derivatives were prepared. The metal complexes of the glyoximes such as Cu(II), Ni(II) and Co(II) were also prepared. The structures of these ligands and their complexes were identified by FT-IR, 1H NMR and 13C NMR spectral data, elemental analysis and magnetic measurements.