Journals / Turkish Journal of Chemistry / 2014 / Cilt: 38 - Sayı: 6
Water-soluble phthalocyanines containing azo dye; microwave-assisted synthesis and photochemical properties of ZnPcs
- Journal
- Turkish Journal of Chemistry
- Pages
- 1185–1200
- DOI
- —
Abstract
Novel water-soluble metallophthalocyanines (M: Co, Ni, Cu, Zn) containing azo dye were characterized. The structures were confirmed by IR, UV/vis, 1H NMR, 13C NMR, mass spectroscopy, and elemental analysis. Photochemical properties and aggregation behavior of zinc phthalocyanines were investigated. Singlet oxygen quantum yields of the zinc phthalocyanines (2d, 3d, 5d, and 6d) were 0.8, 0.57, 0.71, and 0.46, respectively.
Özet
Novel water-soluble metallophthalocyanines (M: Co, Ni, Cu, Zn) containing azo dye were characterized. The structures were confirmed by IR, UV/vis, 1H NMR, 13C NMR, mass spectroscopy, and elemental analysis. Photochemical properties and aggregation behavior of zinc phthalocyanines were investigated. Singlet oxygen quantum yields of the zinc phthalocyanines (2d, 3d, 5d, and 6d) were 0.8, 0.57, 0.71, and 0.46, respectively.