Journals / Turkish Journal of Chemistry / 2014 / Cilt: 38 - Sayı: 1

Self-condensation reactions of acyl phosphonates: synthesis of tertiary O-protected a-hydroxyphosphonates

Pages
164–171
DOI
—

Abstract

The self-condensation reaction of benzoyl dialkyl phosphonates was developed using cyanide ion as catalyst, affording versatile tertiary O-protected a-hydroxy phosphonates in moderate yield.

Özet

The self-condensation reaction of benzoyl dialkyl phosphonates was developed using cyanide ion as catalyst, affording versatile tertiary O-protected a-hydroxy phosphonates in moderate yield.

Keywords: Acyl phosphonates, tertiary a-hydroxy phosphonates, phosphonate-phosphate rearrangement