Journals / Sigma Journal of Engineering and Natural Sciences / 2019 / Cilt: 37 Sayı: 4

ELECTROCHEMICAL STUDIES OF ZINC DEPOSITION CONDITIONS

Pages
1262–1273
Publication Date
2019-12-01
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The study of the influence of deposition potential on corrosion behaviour in 3.5% NaCl, solution indicated that Zn film obtained at -1.26V presented less corrosion current and bestcorrosion resistance.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:Zinc films are deposited on steel from sulphate bath using electrodeposition process.
📊
Key Findings & Data:Furthermore, potentiodynamic polarisation and electrochemical impedance spectroscopyare used to study corrosion behaviour of zinc films.The pH of the bath was controlled at 4, for decreasinghydrogen evolution reaction,and increasing current efficiency of the Zn deposition.
💡
Conclusion & Impact:The study of the influence of deposition potential on corrosion behaviour in 3.5% NaCl, solution indicated that Zn film obtained at -1.26V presented less corrosion current and bestcorrosion resistance.
🔬Design:Modeling & Simulation
📍Scope:Comprehensive Sample
⚙️Variables:Zinc films · electrodeposition · deposition potential

Abstract

Zinc films are deposited on steel from sulphate bath using electrodeposition process. Cyclic voltammetry and chronoamperometry are used to study the effect of pH on zinc electrodeposition process and nucleation model respectively. Furthermore, potentiodynamic polarisation and electrochemical impedance spectroscopyare used to study corrosion behaviour of zinc films.The pH of the bath was controlled at 4, for decreasinghydrogen evolution reaction,and increasing current efficiency of the Zn deposition. The study of the influence of deposition potential on corrosion behaviour in 3.5% NaCl, solution indicated that Zn film obtained at -1.26V presented less corrosion current and bestcorrosion resistance.

🔖

Cite This Article

FAID, H. (2019). ELECTROCHEMICAL STUDIES OF ZINC DEPOSITION CONDITIONS. Sigma Journal of Engineering and Natural Sciences, Cilt: 37 Sayı: 4, 1262–1273. https://ajindex.com/articles/897625

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (15)

  1. Abbott A.P, Barron J.C, Frisch G, Ryder K.S, Silva A.F, (2011)The effect of additives on zinc electrodeposition from deep eutectic solvents, ElectrochimActa56, 5272-5279
  2. Abbott A.P, Barron J.C, Frisch G, Gurman S, Ryder K.S, Silva A.F., (2011) Double layer effects on metal nucleation in deep eutectic solvents, PhysChem 13, 10224-10231
  3. Boiadjieva T, Monev M, Tomandl A, Kronberger H, Fafilekal G., (2009) Electrochemical studies on Zn deposition and dissolution in sulphate electrolyte, J Solid State Electrochem 13, 671-677
  4. Bockris J. O’M, Khan S. U. M, W., (1993) Surface Electrochemistry, a Molecular Level Approach, Surface Electrochemistry, Plenum Press, New York
  5. Cantwell P.A, Chung P.P, Jiang H, Wilcox G.D, Critchlow G.W (2009)Corrosion from the Nanoscaleto the Plant, Proceedings of Eurocorr, Nice, France, September
  6. Cachet C., Wiart R., (1990) Zinc deposition and passivated hydrogen evolution in highly acidic sulphate electrolytes: Depassivation by nickel impurities, J Appl Electrochem20, 1009-1014
  7. Cachet C., Wiart R., (1994) Zinc Electrowinning in Acidic Sulfate Electrolytes: Impedance Analysis and Modeling of the Influence on Nickel Impurities, J Electrochem Soc 141, 131-140
  8. Epelboin I, Ksouri M, Wiart R., (1975) On a Model for the Electrocrystallization of Zinc Involving an Autocatalytic Step, ElectrochemSoc122, 1206-2014
  9. Epelboin I., Ksouri M., Lejay E., Wiart R., (1975) A study of the elementary steps of electron-transfer during the electrocrystállization of zinc, ElectrochimActa20, 603-605
  10. Elkhatabi F., Barcelo G., Sarret M., Muller C., (1996) Electrochemical oxidation of zinc + nickel alloys in ammonium baths, J ElectroanalChem 419, 71-76
  11. Gomes A., Pereira M.I.S., (2006) Zn electrodeposition in the presence of surfactants: Part I. Voltammetric and structural studies, ElectrochimActa52, 863-871
  12. Gunawardena G., Hills G., Montenegro I., Scharifker B., (1982)Electrochemical nucleation: Part I. General considerations, J. of ElectroanChem and Inter Electrochem 138, 225-239
  13. Ibrahim S., Bakkar A., Ahmed E., Selim A., (2016) Effect of additives and current mode on zinc electrodeposition from deep eutectic ionic liquids, ElectrochimActa 191, 724–732
  14. Ichino R., Cachet C., Wiart R., (1996) Mechanism of zinc electrodeposition in acidic sulfate electrolytes containing Pb2+ ions,ElectrochimActa41, 1031-1039
  15. Krishnan R.M., Natarajan S.R., Muralidharan V.S., Singh G., (1992) Characteristi