Journals / Sigma Journal of Engineering and Natural Sciences / 2020 / Cilt: 38 Sayı: 2

MODELING AND OPTIMIZATION OF ZINC RECOVERY FROM ENYIGBA SPHALERITE IN A BINARY SOLUTION OF ACETIC ACID AND HYDROGEN PEROXIDE

Pages
589–601
Publication Date
2021-06-01
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Hence, ANN demonstrated higher predictive capability than RSM.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:This work focused on the modeling and optimization of zinc recovery from sphalerite in a binary solution of acetic acid and hydrogen peroxide.
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Key Findings & Data:RSM modeling gave optimum conditions of 90oC leaching temperature, 6M acid concentration, 540 rpm stirring rate, 120 minutes leaching time and 6M hydrogen peroxide concentration; at which about 89.91% zinc was recovered.
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Conclusion & Impact:Hence, ANN demonstrated higher predictive capability than RSM.
🔬Design:Modeling & Simulation
📍Scope:Comprehensive Sample
⚙️Variables:Sphalerite · acetic acid · hydrogen peroxide

Abstract

This work focused on the modeling and optimization of zinc recovery from sphalerite in a binary solution of acetic acid and hydrogen peroxide. The sphalerite sample was characterized using X-ray fluorescence (XRF), X-ray diffraction (XRD) and Scanning electron micrograph (SEM). The result revealed that the ore exists as zinc sulphide (ZnS). Levenberg-Marquardt (LM) back-propagation algorithm was employed for artificial neural network (ANN) modeling while central composite rotatable design (CCRD) was deployed for response surface methodology (RSM) modeling. RSM modeling gave optimum conditions of 90oC leaching temperature, 6M acid concentration, 540 rpm stirring rate, 120 minutes leaching time and 6M hydrogen peroxide concentration; at which about 89.91% zinc was recovered. Comparison of the two modeling techniques revealed that ANN (root mean square error, RMSE = 0.530, absolute average deviation, AAD = 0.681, coefficient of determination = 0.996) gave better predictions than RSM (root mean square error, RMSE = 0.755, absolute average deviation, AAD = 0.841, coefficient of determination = 0.991). Hence, ANN demonstrated higher predictive capability than RSM.

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Cite This Article

NNANWUBE, I. A., UDEAJA, J. N., ONUKWULI, O. D. (2021). MODELING AND OPTIMIZATION OF ZINC RECOVERY FROM ENYIGBA SPHALERITE IN A BINARY SOLUTION OF ACETIC ACID AND HYDROGEN PEROXIDE. Sigma Journal of Engineering and Natural Sciences, Cilt: 38 Sayı: 2, 589–601. https://ajindex.com/articles/897527

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