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Journals / Gümüşhane Üniversitesi Fen Bilimleri Dergisi / 2023 / Cilt: 13 - Sayı: 2

New Mixed Ni(II), Cu(II), and Co(II) Complexes derived from 2-((2-mercaptophenylimino)methyl)-4-methoxyphenol and 1,10-Phenanthroline: Synthesis and Characterization

2-((2-merkaptofenilimino)metil)-4-metoksifenol ve 1,10-fenantrolinden Türetilen Yeni Karışık Ni(II), Cu(II) ve Co(II) Kompleksleri: Sentez ve Karakterizasyon

Hatice Gamze SOĞUKÖMEROĞULLARI
Ahmet Oral SARIOĞLU
Pages
350–358
Publication Date
2023-04-15
DOI
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

There are no conductivity properties in the complexes; however, they exhibit molar conductivities that range from 2.46 to 9.04 µS/cm.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:Three new mixed Ni(II), Co(II) and Cu(II) complexes have been created using 2-((2-mercaptophenylimino)methyl)-4-methoxyphenol and 1,10-phenanthroline.
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Key Findings & Data:Magnetic susceptibility readings for the L-Cu, L-Ni, and L-Co complexes were 1.97 BM, 2.92 BM, and 2.84 BM, respectively.
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Conclusion & Impact:There are no conductivity properties in the complexes; however, they exhibit molar conductivities that range from 2.46 to 9.04 µS/cm.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Karışık Ligand Metal kompleksi · Schiff baz · 10-fenantrolin

Abstract

Three new mixed Ni(II), Co(II) and Cu(II) complexes have been created using 2-((2-mercaptophenylimino)methyl)-4-methoxyphenol and 1,10-phenanthroline. FT-IR, Elemental analysis, magnetic susceptibility, UV-Vis and molar conductivity technique have all been used to explore the structural characterisation of these compounds. Magnetic susceptibility readings for the L-Cu, L-Ni, and L-Co complexes were 1.97 BM, 2.92 BM, and 2.84 BM, respectively. The L-Co complex is thought to be antiferromagnetic. The structures of the mixed ligand metal complexes are thought to be octahedral geometry. There are no conductivity properties in the complexes; however, they exhibit molar conductivities that range from 2.46 to 9.04 µS/cm.

Özet

2-((2-merkaptofenilimino)metil)-4-metoksifenol ve 1,10-fenantrolinden üç yeni karışık Ni(II), Co(II) ve Cu(II) kompleksi sentezlenmiştir. Bu bileşiklerin yapısal karakterizasyonu, FT-IR, elementel analiz, manyetik duyarlılık, UV-Vis ve molar iletkenlik teknikleri kullanılarak araştırılmıştır. Manyetik duyarlılık ölçümleri L-Cu, L-Ni ve L-Co kompleksleri için sırasıyla 1.97 BM, 2.92 BM, ve 2.84 BM olarak kaydedilmiştir. L-Co kompleksinin antiferromanyetik özellikte olduğu düşünülmektedir. Karışık ligand metal komplekslerinin yapılarının oktahedral geometriye sahip olduğu düşünülmektedir. Komplekslerin molar iletkenlik değerleri 2.46-9.04 μS/cm arasında olduğundan dolayı iletkenlik göstermemektedir.

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Cite This Article

SOĞUKÖMEROĞULLARI, H. G., SARIOĞLU, A. O. (2023). New Mixed Ni(II), Cu(II), and Co(II) Complexes derived from 2-((2-mercaptophenylimino)methyl)-4-methoxyphenol and 1,10-Phenanthroline: Synthesis and Characterization. Gümüşhane Üniversitesi Fen Bilimleri Dergisi, Cilt: 13 - Sayı: 2, 350–358. https://ajindex.com/articles/886166

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