Journals / Manas Journal of Engineering / 2022 / Cilt: 10 - Sayı: 2

Development and application of bimetallic catalysts supported carbon nanotube for 1-propanol electrooxidation

Pages
134–140
Publication Date
2022-12-31
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

However, it is concluded that PtBi(90:10)/CNT catalyst can be used as an anode catalyst in 1-propanol electrooxidation with long-term stability and low resistance.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:Herein, carbon nanotube supported bimetallic catalysts (PtBi/CNT) are synthesized at various metals weight loadings by NaBH4 reduction method.
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Key Findings & Data:According to XRD results, the crystal size of PtBi(90:10)/CNT catalyst is determined as 4.66 nm.
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Conclusion & Impact:However, it is concluded that PtBi(90:10)/CNT catalyst can be used as an anode catalyst in 1-propanol electrooxidation with long-term stability and low resistance.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:catalyst · 1-propanol · electrooxidation

Abstract

Herein, carbon nanotube supported bimetallic catalysts (PtBi/CNT) are synthesized at various metals weight loadings by NaBH4 reduction method. The surface morphology and crystal structure of the catalysts are investigated via X-ray diffraction (XRD) and electron microscopy with energy dispersive X-ray (SEM-EDX) advance surface methods. According to XRD results, the crystal size of PtBi(90:10)/CNT catalyst is determined as 4.66 nm. Cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and chronoamperometry (CA) electrochemical techniques are used to determine 1-propanol electrooxidation activities of the catalysts. The highest specific activity and mass activity are obtained with PtBi(90:10)/CNT catalyst as 5.663 mA/cm2 and 447.21 mA/mg Pt, respectively. However, it is concluded that PtBi(90:10)/CNT catalyst can be used as an anode catalyst in 1-propanol electrooxidation with long-term stability and low resistance.

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Cite This Article

KAYA, Ş. (2022). Development and application of bimetallic catalysts supported carbon nanotube for 1-propanol electrooxidation. Manas Journal of Engineering, Cilt: 10 - Sayı: 2, 134–140. https://ajindex.com/articles/861069

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References (1)

  1. . Wang C.Q., Zhang K., Xu H., Du Y.K., Goh M.C., “Anchoring gold nanoparticles on poly(3,4-ethylenedioxythiophene) (PEDOT) nanonet as three-dimensional electrocatalysts toward ethanol and 2- propanol oxidation”, Journal of Colloid and Interface Science, 541, (2019), 258-268. [2]. Figueiredo M.C., Sorsa O., Doan N., Pohjalainen E., Hildebrand H., Schmuki P., Wilson B.P., Kallio T., “Direct alcohol fuel cells: Increasing platinum performance by modification with sp-group metals”, Journal of Power Sources, 275, (2015), 341-350. [3]. Hu S.Z., Munoz F., Noborikawa J., Haan J., Scudiero L., Ha S., “Carbon supported Pd-based bimetallic and trimetallic catalyst for formic acid electrochemical oxidation”, Applied Catalysis B- Environmental, 180, (2016), 758-765. [4]. Ulas B., Caglar A., Sahin O., Kivrak H., “Composition dependent activity of PdAgNi alloy catalysts for formic acid electrooxidation”, Journal of Colloid and Interface Science, 532, (2018), 47-57. [5]. Kazici H.C., Yilmaz S., Sahan T., Yildiz F., Er O.F., Kivrak H., “A comprehensive study of hydrogen production from ammonia borane via PdCoAg/AC nanoparticles and anodic current in alkaline medium: experimental design with response surface methodology”, Frontiers in Energy, 14(3), (2020), 578-589. [6]. Kivrak H., Atbas D., Alal O., Cogenli M.S., Bayrakceken A., Mert S.O., Sahin O., “A complementary study on novel PdAuCo catalysts: Synthesis, characterization, direct formic acid fuel cell application, and exergy analysis”, International Journal of Hydrogen Energy, 43(48), (2018), 21886-21898. [7]. Baronia R., Goel J., Baijnath, Kataria V., Basu S., Singhal S.K., “Electro-oxidation of ethylene glycol on Pt-Co metal synergy for direct ethylene glycol fuel cells: Reduced graphene oxide imparting a notable surface of action”, International Journal of Hydrogen Energy, 44(20), (2019), 10023-10032. [8]. Ulas B., Caglar A., Kivrak H., “Determination of optimum Pd:Ni ratio for PdxNi100-x/CNTs formic acid electrooxidation catalysts synthesized via sodium borohydride reduction method”, International Journal of Energy Research, 43(8), (2019), 3436-3445. [9]. Qi Z.G., Kaufman A., “Performance of 2-propanol in direct-oxidation fuel cells”, Journal of Power Sources, 112(1), (2002), 121-129. [10]. Serov A., Martinez U., Falase A., Atanassov P., “Highly active Pd-Cu catalysts for electrooxidation of 2-propanol”, Electrochemistry Communications, 22, (2012), 193-196. [11]. Zhou W.Q., Wang C.Y., Xu J.K., Du Y.K., Yang P.,