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Journals / Selçuk Üniversitesi Fen Fakültesi Fen Dergisi / 2022 / Cilt: 48 - Sayı: 2

Synthesis of Versatile s-Triazine Ligands and Investigation of Salen/Salophen Fe(III)/Cr(III) Metal Complexes

Çok Yönlü s-Triazin Ligandlarinin Sentezi ve Salen/Saloph Fe(III)/Cr(III) Metal Komplekslerinin İncelenmesi

Figen AYDEMİR
Ziya Erdem KOÇ
Pages
98–105
Publication Date
2022-10-01
DOI
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⚡ TL;DR(Too Long; Didn't Read)

Dissolved in ethanol 2,4,6-tris(3,5-dicarboxyphenoxy)-s-triazines ligands dissolved in ethanol ligand complexes [Fe(salen/saloph)]2O, [Cr(salen/saloph)]2O by the addition of double-oxygen-coordinated, synthesis of complexes with monopodal/dipodal was performed in conclusion, two different ligands and this ligands of salen/salophenFe(III)/Cr(III) complexes were isolated and their structures were characterized by FT-IR and 1H NMR spectra, elemental analysis and magnetic susceptibility.

📌 3 Key Takeaways

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Objective & Hypothesis:In this study, cyanuric chloride was used as a starting material.
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Key Findings & Data:Cyanuric chloride, given in the literature making use of methods in acetone end of the 5-hydroxyisophtalic acid chloride using 0 oC onedirectional (monopodal) 2,4-dichloro-6-(3,5-dicarboxyphenoxy)-1,3,5-triazine (MNCHIPA) and at room temperature bidirectional (dipodal) 2-chloro-4,6-(2,5-dicarboxyphenylphenoxy)-1,3,5-triazine (DPCHIPA) compounds were synthesized.
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Conclusion & Impact:Dissolved in ethanol 2,4,6-tris(3,5-dicarboxyphenoxy)-s-triazines ligands dissolved in ethanol ligand complexes [Fe(salen/saloph)]2O, [Cr(salen/saloph)]2O by the addition of double-oxygen-coordinated, synthesis of complexes with monopodal/dipodal was performed in conclusion, two different ligands and this ligands of salen/salophenFe(III)/Cr(III) complexes were isolated and their structures were characterized by FT-IR and 1H NMR spectra, elemental analysis and magnetic susceptibility.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:s-triazine · siyanür klorür · 5-hidroksiizoftalik asit

Abstract

In this study, cyanuric chloride was used as a starting material. Cyanuric chloride, given in the literature making use of methods in acetone end of the 5-hydroxyisophtalic acid chloride using 0 oC onedirectional (monopodal) 2,4-dichloro-6-(3,5-dicarboxyphenoxy)-1,3,5-triazine (MNCHIPA) and at room temperature bidirectional (dipodal) 2-chloro-4,6-(2,5-dicarboxyphenylphenoxy)-1,3,5-triazine (DPCHIPA) compounds were synthesized. Dissolved in ethanol 2,4,6-tris(3,5-dicarboxyphenoxy)-s-triazines ligands dissolved in ethanol ligand complexes [Fe(salen/saloph)]2O, [Cr(salen/saloph)]2O by the addition of double-oxygen-coordinated, synthesis of complexes with monopodal/dipodal was performed in conclusion, two different ligands and this ligands of salen/salophenFe(III)/Cr(III) complexes were isolated and their structures were characterized by FT-IR and 1H NMR spectra, elemental analysis and magnetic susceptibility.

Özet

Bu çalışmada çıkış maddesi olarak siyanür klorür kullanıldı. Siyanür klorür, literatürde verilen metotlardan faydalanılarak asetonlu ortamda farklı klor uçlarından 5-hidroksiizoftalik asit kullanılarak 0 oC bir yönlü (monopodal) 2,4-dikloro-6-(3,5-dikarboksifenoksi)-1,3,5-triazin (MNCHIPA) ve oda sıcaklığında iki yönlü (dipodal) 2-kloro-4,6-(2,5-dikarboksifenilfenoksi)-1,3,5-triazin (DPCHIPA) bileşikleri sentezlendi. Etanollü ortamda çözülmüş, ligandlara ve yine etanolde çözülmüş ligand kompleksleri [Fe(salen/saloph)]2O, [Cr(salen/saloph)]2O ilave edilerek çift oksijenle koordine olmuş monopodal/dipodal komplekslerinin sentezi gerçekleştirildi. Sonuç olarak, monopodal/dipodal-s-triazin ligandı ve bu ligandın salen/salophFe(III)/Cr(III) kompleksleri izole edilerek, elementel analizleri, FT-IR, 1H-NMR spektrumları ve manyetik süssebtibilite ölçümleri alınarak yapıları aydınlatıldı..

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Cite This Article

AYDEMİR, F., KOÇ, Z. E. (2022). Synthesis of Versatile s-Triazine Ligands and Investigation of Salen/Salophen Fe(III)/Cr(III) Metal Complexes. Selçuk Üniversitesi Fen Fakültesi Fen Dergisi, Cilt: 48 - Sayı: 2, 98–105. https://ajindex.com/articles/800276

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References (11)

  1. Candlın. J. P., Taylor. K.A. ve Thompson, D. T., 1968, Reactions of Transition Metal Complexes, Elsevier, 87. Celikbilek, S. ve Koc, Z. E., 2014, Investigation of Dipodal oxy-Schiff base and its salen and salophen Fe(III)/Cr(III)/Mn(III) Schiff bases (N2O2) caped complexes and their magnetic and thermal behaviors, Journal of Molecular Structure, 1065, 205-209.
  2. Koc, Z. E. ve Ucan, H. I., 2007, Complexes of iron(III) salen and saloph Schiff bases with bridging 2,4,6-tris(2,5dicarboxyphenylimino-4-formylphenoxy)-1,3,5-triazine and 2,4,6-tris(4-carboxyphenylimino-4'-formylphenoxy)-1,3,5-triazine, Transition Metal Chemistry, 32 (5), 597-602.
  3. Koc, Z. E. ve Ucan, H. I., 2008, Complexes of Iron(III) and Chrom(III) Salen and Saloph Schiff Bases with Bridging 2,4,6-tris(4-nitrophenylimino-4'-formylphenoxy)-1,3,5-triazine, Journal of Macromolecular Science Part a-Pure and Applied Chemistry, 45 (12), 1074-1079.
  4. Koc, Z. E. ve Uysal, S., 2010, Synthesis and Characterization of Dendrimeric Bridged Salen/Saloph Complexes and Investigation of Their Magnetic and Thermal Behaviors, Helvetica Chimica Acta, 93 (5), 910-919.
  5. Koc, Z. E., 2011, Complexes of Iron(III) and Chromium(III) Salen and Salophen Schiff Bases with Bridging 1,3,5-Triazine Derived Multidirectional Ligands, Journal of Heterocyclic Chemistry, 48 (4), 769-775.
  6. Koc, Z. E. ve Uysal, S., 2011, Synthesis and Characterization of Tripodal Oxy-Schiff base (2,4,6-Tris(4-Carboxymethylenephenylimino-4 '-formylphenoxy)-1,3,5-triazine) and the Thermal and Magnetic Properties of its Fe(III)/Cr(III) Complexes, Journal of Inorganic and Organometallic Polymers and Materials, 21 (3), 400-406.
  7. Koc, Z. E. ve Uysal, A., 2016, Investigation of novel monopodal and dipodal oxy-Schiff base triazine from cyanuric chloride: Structural and antimicrobial studies, Journal of Macromolecular Science Part a-Pure and Applied Chemistry, 53 (2), 111-115.
  8. Kopel, P., Sindelar, Z. ve Klicka, R., 1998, Complexes of iron(III) salen and saloph Schiff bases with bridging dicarboxylic and tricarboxylic acids, Transition Metal Chemistry, 23 (2), 139-142.
  9. Tahmassebi, D. C. ve Sasaki, T., 1994, Synthesis of a New Trialdehyde Template for Molecular Imprinting, Journal of Organic Chemistry, 59 (3), 679-681.
  10. Tahmassebi, D. C. ve Sasaki, T., 1998, Synthesis of a three-helix bundle protein by reductive amination, Journal of Organic Chemistry, 63 (3), 728-731.
  11. Tan, N. ve Bekaroğlu, Ö., 1983, Synthesis of some organometalik compounds of 1,2-acenaphtylene-dione d