Based on these results, it is concluded that BPCPFA with extended conjugated system has good and promising photovoltaic performance with Voc value as 0.96 V.
📌 3 Key Takeaways
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Objective & Hypothesis:A new acrylonitrile derivative 3 (BPCPFA) which offer potential application as organic solar cell material was synthesized with three steps.
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Key Findings & Data:Theoretical prediction and experimental studies for photovoltaic performance were performed.
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Conclusion & Impact:Based on these results, it is concluded that BPCPFA with extended conjugated system has good and promising photovoltaic performance with Voc value as 0.96 V.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Conjugated systems · nitriles · organic solar cells
Abstract
A new acrylonitrile derivative 3 (BPCPFA) which offer potential application as organic solar cell material was synthesized with three steps. The structures of the molecules synthesized in these steps were characterized using various spectral analyses. BPCPFA was investigated as an electron acceptor molecule in next generation organic solar cells. Theoretical prediction and experimental studies for photovoltaic performance were performed. Based on these results, it is concluded that BPCPFA with extended conjugated system has good and promising photovoltaic performance with Voc value as 0.96 V.
YORUR-GORECİ, C., KAZİCİ, M., BOZAR, S., DEMİR, Z., TORAMAN, A., ONGUL, F., ALİ, A., GUNES, S. (2017). A NOVEL ACRYLONITRILE DERIVATIVE HAVING PHOTOVOLTAIC PERFORMANCE. Journal of the Turkish Chemical Society Section A: Chemistry, Cilt: 3 - Sayı: 3, 439–452. https://ajindex.com/articles/781674
Bloking J, T,Han X,Higgs A, T,Kastrop J, P,Pandey L,Norton J, E,Risko C,Chen C, E,Brédas J,L,McGehee M, D, Sellinger A. Solution-processed organic solar cells with power conversion efficiencies of 2.5% using benzothiadiazole/ımide-based acceptors. Chemistry of Materials. 2011
5484−5490.DOI: 10.1021/cm203111k. Gunes S, Neugebauer H, Sariciftci N, S. Conjugated polymer-based organic solar cells. Chemical Reviews. 2007
1324–1338. DOI:10.1021/cr050149z. Brabec C J, Gowrisanker S, Halls J J M, Laird D, Jia S, Williams S, P. Polymer-fullerene bulk-heterojunction solar cells. Advanced Materials. 2010
3839–3856. DOI:10.1002/adma.200903697. Linac Y, and Zhan X. Non-fullerene acceptors for organic photovoltaics: an emerging horizon. Materials Horizons. 2014
DOI: 10.1039/c4mh00042k. Babu D, D, Gachumale S, R, Anandan S, Adhikari A, V. New D-π-A type indole based chromogens for DSSC: design, synthesis and performance studies. Dyes and Pigment. 2015
183–191. DOI:10.1016/j.dyepig.2014.07.006. Liang Y, Xu Z, Xia J, Tsai S, T, Wu Y, Li G, Ray C, Yu L. For the bright future-bulk heterojunction polymer solar cells with power conversion efficiency of 7.4%. Advanced Energy Materials.2010
135–138. DOI: 10.1002/adma.200903528. Kazici M, Bozar S, Aydin-Yuksel S, Ongul F, Gokce H, Gunes S, Yorur-Goreci C. Nanotechnology theoretical and experimental investigations of a 2-(4-chlorophenyl)-3-{[5-(2-cyano-2- phenylethenyl)]furan-2-yl}acrylonitrile molecule as a potential acceptor in organic solar cells. Nanotechnology. 2016
234003 (9pp). DOI:10.1088/0957-4484/27/23/234003. Eftaiha A F, Sun J-P, Hill I, G, Welch G, C. Recent advances of non-fullerene, small molecular acceptors for solution processed bulk heterojunction solar cells. Journal of Materials Chemistry A. 2014
1201–1213. DOI: 10.1039/C3TA14236A. Mishra A, Bäuerle P. Small molecule organic semiconductors on the move: promises for future solar energy technology. Angewandte Chemie International Edition. 2012
2020–2067. DOI:10.1002/anie.201102326. Lu S-Li, Yang M-J, Bai F-L. Synthesis, Electrochemical, and Optical Properties of a Novel PPV/PPE Block-Copolymer. Macromolecular Rapid Communications. 2004
DOI:10.1002/marc.200400004. Xu Y, Zhang H, Li F, Shen F, Wang H, Li X, Yu Y, Ma Y. Supramolecular interaction-induced self-assembly of organic molecules into ultra-long tubular crystals with wave guiding and amplified spontaneous emission. Journal of Materials Chem