SavedAdd your journal

Journals / Journal of the Turkish Chemical Society Section A: Chemistry / 2020 / Cilt: 7 - Sayı: 1

The Synthesis of New Phosphazene-Bearing Ethyl p-Hydroxybenzoate and Ferrocenyl Pendant Groups and their Spectroscopic and Crystallographic Characterizations

Yasemin TÜMER
Mahmut ÇAYIRBAŞI
Onur ŞAHİN
Tuncer HÖKELEK
Pages
215–224
Publication Date
2020-02-15
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The structure of the two compounds (2 and 5) are elucidated by X-ray diffraction techniques.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:Herein, we report a study of novel hexachlorocyclotriphosphazene (N3P3Cl6) derivatives bearing ethyl p-hydroxy benzoate and pendant ferrocenyl groups.
📊
Key Findings & Data:Characterizations of the products [mono- 2, di- (geminal 3a; non-geminal transa-3b, transb-3c and cis-3d), tri- 4 and tetra- 5 substitue phosphazene derivatives] were performed using elemental analysis and spectral methods.
💡
Conclusion & Impact:The structure of the two compounds (2 and 5) are elucidated by X-ray diffraction techniques.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Ferrocenylphosphazenes · ethyl p-hydroxy benzoate · crystal structure

Abstract

Herein, we report a study of novel hexachlorocyclotriphosphazene (N3P3Cl6) derivatives bearing ethyl p-hydroxy benzoate and pendant ferrocenyl groups. Characterizations of the products [mono- 2, di- (geminal 3a; non-geminal transa-3b, transb-3c and cis-3d), tri- 4 and tetra- 5 substitue phosphazene derivatives] were performed using elemental analysis and spectral methods. The structure of the two compounds (2 and 5) are elucidated by X-ray diffraction techniques.

🔖

Cite This Article

TÜMER, Y., ÇAYIRBAŞI, M., ŞAHİN, O., HÖKELEK, T. (2020). The Synthesis of New Phosphazene-Bearing Ethyl p-Hydroxybenzoate and Ferrocenyl Pendant Groups and their Spectroscopic and Crystallographic Characterizations. Journal of the Turkish Chemical Society Section A: Chemistry, Cilt: 7 - Sayı: 1, 215–224. https://ajindex.com/articles/781253

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (11)

  1. Chandrasekhar V, Narayanan RS, Mamidala R, Venkatasubbaiah K. Phosphazenes. In Organophosphorus Chemistry Volume 47, Eds. Allen, DW, Loakes, D and Tebby, JC. Royal Society of Chemistry, Cambridge, UK; 2018, 363-424
  2. Stewart FF. Phosphazenes. In Organophosphorus Chemistry Volume 44, Eds.: Allen DW, Loakes D, Tebby JC. Royal Society of Chemistry, Cambridge, UK; 2015, 397-430
  3. Chandrasekhar V, Krishnan V. Advances in the chemistry of chloro-cyclophosphazenes. Advances in Inorganic Chemistry. 2002;53:159-211
  4. Beşli S, Coles SJ, Coles LS, Davies DB, Kılıç A. Investigation of a spiro to ansa rearrangement with di-functional alcohols in cyclotriphosphazene derivatives. Polyhedron. 2012;43:176–84
  5. Türe S. Phosphorus-nitrogen compounds: Reinvestigation of the reactions of hexachlorocyclotriphosphazene with 1,4-butane- and 1,6-hexane-diols—NMR studies of the products. Phosphorus, Sulfur, and Silicon and the Related Elements. 2016;191(8): 1174-82
  6. Muralidharan K, Elias A. Preparation of the First Examples of Ansa−Spiro Substituted Fluorophosphazenes and Their Structural Studies: Analysis of C−H···F−P Weak Interactions in Substituted Fluorophosphazenes. Inorg. Chem. 2003;42:7535–43
  7. Koran K, Tekin Ç, Biryan F, Tekin S, Sandal S, Görgülü AO. Synthesis, structural and thermal characterizations, dielectric properties and in vitro cytotoxic activities of new 2,2,4,4-tetra(4′-oxy-substituted-chalcone)-6,6-diphenylcyclotriphosphazene derivatives. Medicinal Chemistry Research. 2017;26(5):962-74
  8. Tümer Y, Şehirli E, Yüksektepe Ataol Ç. Syntheses and Structural Characterizations of First Paraben Substituted Ferrocenyl Phosphazene Compounds. JOTCSA. 2017;4(1):299-312
  9. Tümer Y, Koç LY, Asmafiliz N, Kılıç Z, Hökelek T, Soltanzade H, Açık L, Yola ML, Solak AO. Phosphorus–nitrogen compounds: Part 30. Syntheses and structural investigations, antimicrobial and cytotoxic activities and DNA interactions of vanillinato-substituted NN or NO spirocyclic monoferrocenyl cyclotriphosphazenes. J. Biol. Inorg. Chem. 2015;20:165-78
  10. Kundu A, Hariharan PS, Prabakaran K, Anthony SP. Synthesis of new colori/ A fluorimetric chemosensor for selective sensing of biologically important Fe3+, Cu2+ and Zn2+ metal ions. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2015;151:426–31
  11. Yenilmez Çiftçi G, Şenkuytu E, Bulut M, Durmuş M. Novel Coumarin Substituted Water Soluble Cyclophosphazenes as “Turn-Off” Type Fluorescence Chemosensors for Detection