SavedAdd your journal

Journals / Journal of the Turkish Chemical Society Section A: Chemistry / 2021 / Cilt: 8 - Sayı: 1

Usage of Cellulose Acetate Butyrate Based Oligomeric Structures on Cotton Fabric Coatings

Zehra YILDIZ
Hacer Ayşen ÖNEN
Ozan Gazi DEHMEN
Atilla GÜNGÖR
Pages
303–310
Publication Date
2021-02-28
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Results proved that the best washing process in fibrillation was found as enzymatic washing due to the having the highest adhesion strength and the least deformation against abrasion.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:In this study, the hydroxyl groups of cellulose acetate butyrate (CAB) oligomer were reacted with toluene diisocyanate-hydroxyethyl methacrylate (TDI-HEMA) adduct, in order to improve properties of CAB such as flexibility, thermal stability etc.
📊
Key Findings & Data:Then the obtained modified CAB oligomer was characterized by FTIR and 1H NMR analysis.
💡
Conclusion & Impact:Results proved that the best washing process in fibrillation was found as enzymatic washing due to the having the highest adhesion strength and the least deformation against abrasion.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:UV-Curing · Cellulose Acetate Butyrate · Cotton Fabric

Abstract

In this study, the hydroxyl groups of cellulose acetate butyrate (CAB) oligomer were reacted with toluene diisocyanate-hydroxyethyl methacrylate (TDI-HEMA) adduct, in order to improve properties of CAB such as flexibility, thermal stability etc. Then the obtained modified CAB oligomer was characterized by FTIR and 1H NMR analysis. UV-curable coating formulations were prepared by using the modified CAB oligomer, and then applied on cotton fabrics in order to reinforce cotton fabrics and make them durable to outdoor environments. Cotton fabrics were treated with a commercial washing detergent, alkali solution, and an enzyme prior to the UV-coating, in order to increase the adhesion between the cotton fabric and coating layer. Washed and coated fabrics were evaluated in terms of absorbency, tensile, and adhesion properties, respectively. Light microscopy was employed to observe the effects of washing processes on fibre, and to show the abrasion deformation on coated fabric. Results proved that the best washing process in fibrillation was found as enzymatic washing due to the having the highest adhesion strength and the least deformation against abrasion.

🔖

Cite This Article

YILDIZ, Z., ÖNEN, H. A., DEHMEN, O. G., GÜNGÖR, A. (2021). Usage of Cellulose Acetate Butyrate Based Oligomeric Structures on Cotton Fabric Coatings. Journal of the Turkish Chemical Society Section A: Chemistry, Cilt: 8 - Sayı: 1, 303–310. https://ajindex.com/articles/781173

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (15)

  1. Çakmakçı E, Güngör A, Kayaman-Apohan N, Kuruca SE, Çetin MB, Dar KA. Cell growth on in situ photo-cross-linked electrospun acrylated cellulose acetate butyrate. Journal of Biomaterials Science, Polymer Edition. 2012;23(7):887-99
  2. Wang X, Huang S, Wang Y, Wei P, Chen Y, Xia Y, et al. Eco-friendly cellulose acetate butyrate/poly (butylene succinate) blends: crystallization, miscibility, thermostability, rheological and mechanical properties. Journal of Polymer Research. 2017;24(2):16
  3. Biniaś W, Biniaś D. Formation of Microfibres from Cellulose Acetate Butyrate by Electrospinning with a Surface Modified in Low-temperature Plasma. Fibres & Textiles in Eastern Europe. 2014
  4. Barszczewska-Rybarek IM. Characterization of urethane-dimethacrylate derivatives as alternative monomers for the restorative composite matrix. Dental Materials. 2014;30(12):1336-44
  5. Lei G, Angeli S, Kristol D, Snyder W. Preparation of new blocked diisocyanate for dental application. Journal of Polymer Science Part A: Polymer Chemistry. 1987;25(2):607-15
  6. Wang SJ, Wang YL, Yang PF, Li TD, editors. Preparation of polyurethane-poly (butyl acrylate) hybrid latexes via miniemulsion polymerization. Applied Mechanics and Materials; 2012: Trans Tech Publ
  7. Wang F, Hu J, Tu W. Study on microstructure of UV-curable polyurethane acrylate films. Progress in organic coatings. 2008;62(3):245-50
  8. Xie J, Zhang N, Guers M, Varadan VK. Ultraviolet-curable polymers with chemically bonded carbon nanotubes for microelectromechanical system applications. Smart materials and structures. 2002;11(4):575
  9. Liu X-D, Sheng D-K, Gao X-M, Li T-B, Yang Y-M. UV-assisted surface modification of PET fiber for adhesion improvement. Applied Surface Science. 2013;264:61-9
  10. Eker P. Farklı Hammaddeler İçeren Lycralı Dokuma Kumaşlarda Biyo-Parlatma ve Biyo-Parlatmanın Kumaş Performansına Etkileri. Adana2012
  11. Ozgen H. Farklı Yöntemlerle Pamuklu Örme Kumaşın Enzimatik Hidrofilleştirilmesi. Bartın2018
  12. Stanescu MD, Dochia M, Radu D, Sirghie C. Green solution for cotton scouring. Fibres & Textiles in Eastern Europe. 2010;18(3):80
  13. SANCAR B, PAKSOY N, BALCI O, KURTOĞLU N. Pamuklu Dokuma Kumaşların Boyamaya Hazırlık İşlemlerinde Enzim Kullanım Olanaklarının İncelenmesi ve Kombine Proses Geliştirilmesi. Tekstil ve Mühendis. 2012;19(86)
  14. Toprak T. Pamuklu Kumaşlarda Kombine Enzim Proseslerinin Geliştirilmesi. Bursa2014
  15. Davulcu A. Pamuklu Kumaşların Ön Terbiye Proseslerinin Enzimatik Yöntem