Journals / Journal of the Turkish Chemical Society Section A: Chemistry / 2022 / Cilt: 9 - Sayı: 4

Dye Sensitized Solar Cell (DSSC) Fabrication Using Methanol Extract of Onion Peel as a Natural Sensitizer

Pages
1285–1294
Publication Date
2022-11-30
DOI
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

A solar energy conversion efficiency of η= 0.0413% was obtained from UME extract with a short circuit current of up to Jsc=0.6031 mAcm-2 and a fill factor of 0.2764.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:Methanol extracts of onion peel waste (Allium cepa) were applied as natural sensitizer in Dye-Sensitized Solar Cell (DSSC) fabrication.
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Key Findings & Data:Dye absorption was characterized by UV-Vis Spectrophotometer at a wavelength of 200-800 nm and FT-IR at a wave number of 4000-500 cm-1.
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Conclusion & Impact:A solar energy conversion efficiency of η= 0.0413% was obtained from UME extract with a short circuit current of up to Jsc=0.6031 mAcm-2 and a fill factor of 0.2764.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:anthocyanin · methanol extract · natural sensitizer

Abstract

Methanol extracts of onion peel waste (Allium cepa) were applied as natural sensitizer in Dye-Sensitized Solar Cell (DSSC) fabrication. This research investigated the dye characteristics of onion peel extract and its power conversion efficiency. Onion peel extraction was carried out using unacidified methanol extract (UME) and acidified methanol extract (AME). Dye absorption was characterized by UV-Vis Spectrophotometer at a wavelength of 200-800 nm and FT-IR at a wave number of 4000-500 cm-1. The power conversion efficiency of the fabricated DSSC was determined by calculating the voltage and current generated by the multimeter. The red onion peel extracts, both acidified and unacidified methanol, had maximum absorption at UV-Visible range (457, 659 and 662 nm). Onion peel extract has several functional groups such as –OH, C=O, C-O-C, C=C, and C-H aromatics- showing specific absorption corresponding to the anthocyanin structure. A solar energy conversion efficiency of η= 0.0413% was obtained from UME extract with a short circuit current of up to Jsc=0.6031 mAcm-2 and a fill factor of 0.2764.

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Cite This Article

ADU, R. E. Y. (2022). Dye Sensitized Solar Cell (DSSC) Fabrication Using Methanol Extract of Onion Peel as a Natural Sensitizer. Journal of the Turkish Chemical Society Section A: Chemistry, Cilt: 9 - Sayı: 4, 1285–1294. https://ajindex.com/articles/781000

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References (15)

  1. content-outlook-energi-indonesia-2019-bahasa-indonesia.pdf
  2. Mariotti N, Bonomo M, Fagiolari L, Barbero N, Gerbaldi C, Bella F, et al. Recent advances in eco-friendly and cost-effective materials towards sustainable dye-sensitized solar cells. Green Chem. 2020;22(21):7168–218
  3. Heeger AJ. Semiconducting and Metallic Polymers: The Fourth Generation of Polymeric Materials. J. Phys. Chem. B. 2001;105(36):8475-8491
  4. Maddah HA, Berry V, Behura SK. Biomolecular photosensitizers for dye-sensitized solar cells: Recent developments and critical insights. Renewable and Sustainable Energy Reviews. 2020 Apr;121:109678
  5. Akin S. Hysteresis-Free Planar Perovskite Solar Cells with a Breakthrough Efficiency of 22% and Superior Operational Stability over 2000 h. ACS Appl Mater Interfaces. 2019 Oct 30;11(43):39998–40005
  6. Akman E, Akin S. Poly(N,N′‐bis‐4‐butylphenyl‐N,N′‐bisphenyl)benzidine‐Based Interfacial Passivation Strategy Promoting Efficiency and Operational Stability of Perovskite Solar Cells in Regular Architecture. Adv Mater. 2020;9
  7. Ozturk T, Akman E, Shalan AE, Akin S. Composition engineering of operationally stable CsPbI2Br perovskite solar cells with a record efficiency over 17%. Nano Energy. 2021 Sep;87:106157
  8. Shalan AE, Akman E, Sadegh F, Akin S. Efficient and Stable Perovskite Solar Cells Enabled by Dicarboxylic Acid-Supported Perovskite Crystallization. J Phys Chem Lett. 2021 Jan 28;12(3):997–1004
  9. Alami AH, Faraj M, Aokal K, Hawili AA, Tawalbeh M, Zhang D. Investigating Various Permutations of Copper Iodide/FeCu Tandem Materials as Electrodes for Dye-Sensitized Solar Cells with a Natural Dye. 2020;13
  10. Nasyori A, Noor FA. Effect of Natural Dye Extracting Solvents on the Performance of Dye-Sensitised Solar Cells. J Phys: Conf Ser. 2021 Jun 1;1951(1):012027
  11. Wang YC, Cho CP. Improved performance of dye-sensitized solar cells with patterned fluorine-doped tin oxide electrodes. Energy. 2015 Sep;89:277–82
  12. Joy C. A Review- The Potential of Natural Dyes for Dye Sensitized Solar Cells. IJISRT.2017
  13. Ye M, Wen X, Wang M, Iocozzia J, Zhang N, Lin C, et al. Recent advances in dye-sensitized solar cells: from photoanodes, sensitizers and electrolytes to counter electrodes. Materials Today. 2015 Apr;18(3):155–62
  14. Kim JH, Kim DH, So JH, Koo HJ. Toward Eco-Friendly Dye-Sensitized Solar Cells (DSSCs): Natural Dyes and Aqueous Electrolytes. Energies. 2021 Dec 29;15(1):219
  15. Ammar AM, Mohamed HSH, Yousef MMK, Abdel-Hafez GM,