Journals / Turkish Journal of Chemistry / 2003 / Cilt: 27 - Sayı: 3

Crystal Structure of cis-bis(N,N-dimethyl-N'-benzoylthioureato)palladium(II)

Pages
281–286
Publication Date
2003-03-01
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The Pd-S and Pd-O bond lengths are 2.2313(6) and 2.0211(16) Å, respectively.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:In this study cis-bis(N,N-dimethyl-N'-benzoylthioureato) palladium(II) is synthesised and the crystal structure is determined by X-ray diffraction methods.
📊
Key Findings & Data:It crystallises in the space group P21/c, with a = 11.943(1) Å, b = 11.713(1) Å, c = 15.345(1) Å, b = 93.90(1)°, and Dcalc = 1.616 g cm-1 for Z = 4.
💡
Conclusion & Impact:The Pd-S and Pd-O bond lengths are 2.2313(6) and 2.0211(16) Å, respectively.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Complex · X-ray structure · single crystal

Abstract

In this study cis-bis(N,N-dimethyl-N'-benzoylthioureato) palladium(II) is synthesised and the crystal structure is determined by X-ray diffraction methods. It crystallises in the space group P21/c, with a = 11.943(1) Å, b = 11.713(1) Å, c = 15.345(1) Å, b = 93.90(1)°, and Dcalc = 1.616 g cm-1 for Z = 4. The Pd(II) atom is in a four-coordinate geometry consisting of two thiocarbonyl S and two carbonyl O atoms from two ligand groups. The Pd-S and Pd-O bond lengths are 2.2313(6) and 2.0211(16) Å, respectively.

Özet

In this study cis-bis(N,N-dimethyl-N'-benzoylthioureato) palladium(II) is synthesised and the crystal structure is determined by X-ray diffraction methods. It crystallises in the space group P21/c, with a = 11.943(1) Å, b = 11.713(1) Å, c = 15.345(1) Å, b = 93.90(1)°, and Dcalc = 1.616 g cm-1 for Z = 4. The Pd(II) atom is in a four-coordinate geometry consisting of two thiocarbonyl S and two carbonyl O atoms from two ligand groups. The Pd-S and Pd-O bond lengths are 2.2313(6) and 2.0211(16) Å, respectively.

🔖

Cite This Article

AVŞAR, G., ARSLAN, H. (2003). Crystal Structure of cis-bis(N,N-dimethyl-N'-benzoylthioureato)palladium(II). Turkish Journal of Chemistry, Cilt: 27 - Sayı: 3, 281–286. https://ajindex.com/articles/722900

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...