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Journals / Karaelmas Fen ve Mühendislik Dergisi / 2016 / Cilt: 6 - Sayı: 2

Determination of Trace Amounts of Zirconium and Fluoride in Tap Water and BottledWater Samples Using High Performance Liquid Chromatography

Yüksek Performanslı Sıvı Kromatografi ile Musluk Suyu ve Şişelenmiş Su Örneklerinde Zirkonyum ve Florürün Eser Miktarlarının Belirlenmesi

Hale Seçilmiş CANBAY
Güleren ALSANCAK
Pages
321–328
Publication Date
2016-06-01
DOI
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The sensitivity; precision and accuracy of the method are all satisfactory.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:The determination of trace amountsof zirconium and fluoride in various matrixes tap and bottled water were investigated by high performance reversed phase liquid chromatography.
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Key Findings & Data:High performance liquid chromatography HPLC was used for determinationof zirconium and fluoride based on their formed complex with 2- 5-bromo-2-pyridylazo -5-diethylaminophenol 5-Br-PADAP .
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Conclusion & Impact:The sensitivity; precision and accuracy of the method are all satisfactory.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Fluorür · HPLC · PADAP

Abstract

The determination of trace amountsof zirconium and fluoride in various matrixes tap and bottled water were investigated by high performance reversed phase liquid chromatography. High performance liquid chromatography HPLC was used for determinationof zirconium and fluoride based on their formed complex with 2- 5-bromo-2-pyridylazo -5-diethylaminophenol 5-Br-PADAP . Solid-phase extraction SPE along with high performance liquid chromatographywas used for the analysis. Under optimum conditions, the detection limits for Zr IV and flouride were 0.4 ug/L, and 0.015 ug/L, respectively. Recoveries, 99.74–104.33% for Zr IV and 93.33-106.67% for fluoride were obtained. The sensitivity; precision and accuracy of the method are all satisfactory.

Özet

Eser miktarlardaki zirkonyum ve florürün belirlenmesi için, çeşitli matrisler musluk ve şişelenmiş su yüksek performanslı tersfaz sıvı kromatografi ile incelendi. Yüksek performanslı sıvı kromatografisi, zirkonyum ve fluorürün, 2- 5-brom-2-piridilazo -5diethylaminophenol 5-Br-PADAP ile oluşturduğu kompleks üzerinden belirlenmesi için kullanıldı. Katı faz ekstraksiyonu SPE , yüksek performanslı sıvı kromatografisi ile birlikte analiz için kullanıldı. Optimum koşullar altında, Zr IV ve florür için dedeksiyon limitleri sırasıyla 0.4 µg/L ve 0.015 µg/L olarak bulundu. Geri kazanım, Zr IV için % 99.74-104.33 ve florür için % 93.33-106.67 elde edildi. İçme suları, Isparta ve Burdur’un farklı noktalarından toplandı. Şişe suları farklı marketlerden temin edildi. Metodun, duyarlılık, yöntem kesinliği ve doğruluğu parametreleri diğer metodlarla karşılaştırıldığında yeterlidir

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Cite This Article

CANBAY, H. S., ALSANCAK, G. (2016). Determination of Trace Amounts of Zirconium and Fluoride in Tap Water and BottledWater Samples Using High Performance Liquid Chromatography. Karaelmas Fen ve Mühendislik Dergisi, Cilt: 6 - Sayı: 2, 321–328. https://ajindex.com/articles/684033

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