Journals / Turkish Journal of Physics / 2021 / Cilt: 45 - Sayı: 2

Hydrogen sensing properties of Pd loaded TiO2 nanorods

Pages
118–130
Publication Date
2022-11-01
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The effect of temperature dependence on sensor response and the influence of the metal loading forhydrogen sensing are presented and discussed

📌 3 Key Takeaways

🎯
Objective & Hypothesis:The hydrogen sensing performance of palladium (Pd) catalyst loaded TiO2nanorods based sensors wereinvestigated.
📊
Key Findings & Data:TiO2nanorods were grown on Al2O3substrate by a facile hydrothermal process.
💡
Conclusion & Impact:The effect of temperature dependence on sensor response and the influence of the metal loading forhydrogen sensing are presented and discussed
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

The hydrogen sensing performance of palladium (Pd) catalyst loaded TiO2nanorods based sensors wereinvestigated. TiO2nanorods were grown on Al2O3substrate by a facile hydrothermal process. TiO2nanorods (NRs)were functionalized with Pd metal by RF magnetron sputtering. Samples were characterized by X-ray diffraction (XRD)and scanning electron microscopy (SEM) techniques for structural and morphological analysis. Sensor measurementstoward H2and some volatile organic compounds (VOCs) such as acetone, ethanol, xylene and toluene were performedby varying gas concentrations at different temperatures. The sensors were found to exhibit excellent sensitivities towardsdifferent hydrogen concentrations ranging from 25 to 1000 ppm in air. The effects of different operating temperatureson the sensing performance of the devices were studied in the range of 100–200◦C. It was observed that the 2 nm Pd–loaded and 4 nm Pd-loaded sensors were approximately 12 and 44 times more sensitive than the pristine TiO2nanorodssensor, respectively. The effect of temperature dependence on sensor response and the influence of the metal loading forhydrogen sensing are presented and discussed

🔖

Cite This Article

BÜYÜKKÖSE, S. (2022). Hydrogen sensing properties of Pd loaded TiO2 nanorods. Turkish Journal of Physics, Cilt: 45 - Sayı: 2, 118–130. https://ajindex.com/articles/613899

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (10)

  1. Abe JO, Popoola API, Ajenifuja E, Popoola OM. Hydrogen energy, economy and storage: review and recommen-dation. International Journal of Hydrogen Energy 2019
  2. 44 (29) 15072-15086. doi: 10.1016/j.ijhydene.2019.04.068 [2]Liao C, Saito N, Saso Y, Ogawa Y. Flammability limits of combustible gases and vapors measured by a tubularflame method. Fire Safety Journal 1996
  3. 27 (1) 49-68. doi: 10.1016/S0379-7112(96)00021-5 [3]Coward HF, Jones GW. Limits of Flammability of Gases and Vapors, Bureau of Mines Bulletin 503. Washington,USA: U.S. Government Printing Office, 1952. [4]Aziz M, Wijayanta AT, Nandiyanto ABD. Ammonia as effective hydrogen storage: a review on production, storageand utilization. Energies 2020
  4. 13 (12) 3062-3087. doi: 10.3390/en13123062 [5]Dybkjaer IB. Design of Ammonia and Methanol Synthesis Reactors. In: de Lasa H.I. (editor). Chemical ReactorDesign and Technology. NATO ASI Series (Series E: Applied Sciences), vol 110. Dordrecht, The Netherlands:Springer, 1986, pp. 795-819. doi: 10.1007/978-94-009-4400-8_23 [6]Ramachandran R, Menon RK. An overview of industrial uses of hydrogen. International Journal of Hydrogen Energy1998
  5. 23 (7): 593-598. doi: 10.1016/S0360-3199(97)00112-2 [7]Schwandt C, Fray DJ. Hydrogen sensing in molten aluminium using a commercial electrochemical sensor. Ionics2000
  6. 6 (3): 222-229. doi: 10.1007/BF02374070 [8]Miron Y, Smith AC, Lazzara CP. Sealed flask test for evaluating the self-heating tendencies of coals. WashingtonD.C, USA: Dept. of the Interior, Bureau of Mines, 1990. [9]Smith AC, Miron Y, Lazzara CP. Large-scale studies of spontaneous combustion of coal. USA: Dept. of the Interior,Bureau of Mines, 1991. [10]Grimes CA, Ong KG, Varghese OK, Yang X, Mor G et al. A sentinel sensor network for hydrogen sensing. Sensors2003
  7. 3 (3): 69-82. doi: 10.3390/s30300069 [11]Shin W, Matsumiya M, Izu N, Murayama N. Hydrogen-selective thermoelectric gas sensor. Sensors and ActuatorsB: Chemical 2003
  8. 93 (1-3): 304-308. doi: 10.1016/S0925-4005(03)00225-9 [12]Kalanur SS, Lee YA, Seo H. Eye-readable gasochromic and optical hydrogen gas sensor based on CuS–Pd. RSCAdvances 2015
  9. 5 (12): 9028-9034. doi: 10.1039/C4RA11067F [13]Watanabe T, Okazaki S, Nakagawa H, Murata K, Fukuda K. A fiber-optic hydrogen gas sensor with low propagationloss. Sensors and Actuators B: Chemical 2010
  10. 145 (2): 781-787. doi: 10.1016/j.snb.2010.01.040 [14]Christman NT, Hamilton LH. A new chromatographic instrument for measuring trace concentrations of breath-hydr