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Journals / Turkish Journal of Chemistry / 2003 / Cilt: 27 - Sayı: 3

Bromination of 1-cyclopent-1-en-1-ylbenzene and 1-(5-bromocyclopent-1-en-1-yl) benzene and theoretical ınvestigation of the products

Mustafa CEYLAN
Armağan KINAL
Metin BALCI
Yaşar SÜTBEYAZ
Pages
287–294
Publication Date
2022-11-04
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The formation of 11 was explained by the formation of a weakly bridged bromoniun ion of type 9.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:The bromination of 1-cyclopent-1-en-1-ylbenzene (4) in different solvents and at different temperatures was accompanied by the evolution of hydrogen bromide and yielded 1-(5-bromocyclopent-1-en-1-yl)benzene (8).
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Key Findings & Data:Further bromination of 8 gave exclusively 2R(S),5R(S)-1-(1,2,5-tribromocyclopentyl)benzene (11).
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Conclusion & Impact:The formation of 11 was explained by the formation of a weakly bridged bromoniun ion of type 9.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

The bromination of 1-cyclopent-1-en-1-ylbenzene (4) in different solvents and at different temperatures was accompanied by the evolution of hydrogen bromide and yielded 1-(5-bromocyclopent-1-en-1-yl)benzene (8). Further bromination of 8 gave exclusively 2R(S),5R(S)-1-(1,2,5-tribromocyclopentyl)benzene (11). The experimental results were compared with the theoretical ones based on semi-empirical (MM+ and AM1), Hartree-Fock (HF) and density functional theory (DFT). The formation of 11 was explained by the formation of a weakly bridged bromoniun ion of type 9.

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Cite This Article

CEYLAN, M., KINAL, A., BALCI, M., SÜTBEYAZ, Y. (2022). Bromination of 1-cyclopent-1-en-1-ylbenzene and 1-(5-bromocyclopent-1-en-1-yl) benzene and theoretical ınvestigation of the products. Turkish Journal of Chemistry, Cilt: 27 - Sayı: 3, 287–294. https://ajindex.com/articles/602260

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