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Journals / Turkish Journal of Chemistry / 2004 / Cilt: 28 - Sayı: 4

Photophysical properties and electrochemistry of the N,N'-bis-n-butyl derivative of naphthalene diimide

Yusuf DİLGİN
Serap ALP
Sıddık İÇLİ
Banu KÖZ
Yevgen POSOKHOV
Pages
415–424
Publication Date
2022-11-04
DOI
—
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⚡ TL;DR(Too Long; Didn't Read)

It has been found that, in contrast to perylene diimide derivatives, which form $Pi$-electron donor-acceptor complexes with aromatic donor molecules of naphthalene, phenanthrene, pyrene and perylene, BBND does not form $Pi$-electron-donor acceptor complexes with aromatic donor molecules.

📌 3 Key Takeaways

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Objective & Hypothesis:The spectral-luminescent properties and electrochemistry of the N,N'-bis-n-butyl derivative of naphthalene diimide were studied.
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Key Findings & Data:The main photophysical parameters (quantum yield, rate constants of fluorescence and of non-radiative deactivation and fluorescence lifetime) were determined.
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Conclusion & Impact:It has been found that, in contrast to perylene diimide derivatives, which form $Pi$-electron donor-acceptor complexes with aromatic donor molecules of naphthalene, phenanthrene, pyrene and perylene, BBND does not form $Pi$-electron-donor acceptor complexes with aromatic donor molecules.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

The spectral-luminescent properties and electrochemistry of the N,N'-bis-n-butyl derivative of naphthalene diimide were studied. The main photophysical parameters (quantum yield, rate constants of fluorescence and of non-radiative deactivation and fluorescence lifetime) were determined. The LUMO value (-3.51 eV) was determined by cyclic voltammetry. The N,N'-bis-n-butyl derivative of naphthalene diimide (BBND) shows 2 reversible reduction steps (-1.19 V and -1.75 V vs. Ferrocene) in chloroform. Quenching the fluorescence emissions of aromatic donor molecules in acetonitrile revealed the electron acceptor ability of the studied naphthalene diimide derivative. It has been found that, in contrast to perylene diimide derivatives, which form $Pi$-electron donor-acceptor complexes with aromatic donor molecules of naphthalene, phenanthrene, pyrene and perylene, BBND does not form $Pi$-electron-donor acceptor complexes with aromatic donor molecules.

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Cite This Article

DİLGİN, Y., ALP, S., İÇLİ, S., KÖZ, B., POSOKHOV, Y. (2022). Photophysical properties and electrochemistry of the N,N'-bis-n-butyl derivative of naphthalene diimide. Turkish Journal of Chemistry, Cilt: 28 - Sayı: 4, 415–424. https://ajindex.com/articles/602239

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