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Journals / Turkish Journal of Chemistry / 2016 / Cilt: 40 - Sayı: 4

Synthesis and computational studies of new metallo-phthalocyanines bearingdibenzoxanthenes and evaluation of their optical properties in solution and solidPMMA/ZnPc/Al nanocomposite films

Ali Reza KARIMI
Zeinab JAFARZADEH
Meysam SOURINIA
Akbar ZENDEHNAM
Azam KHODADADI
Zeinab DALIRNASAB
Mohammad SOLIMANNEJAD
Peyman ZOLGHARNEIN
Pages
602–612
Publication Date
2022-11-05
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The geometricalstructure of two phthalocyanines was investigated at the RHF/3-21G* computational level.

📌 3 Key Takeaways

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Objective & Hypothesis:New thermally stable metallo-phthalocyanines bearing dibenzoxanthenes as highly organo-solubilizing aro-matic hydrocarbon substituents were successfully prepared by cyclotetramerization of corresponding phthalonitriles withanhydrous metal salts [Zn(CH3COO)2and NiCl2] in the presence of a catalytic amount of DBU in 2-(dimethylamino)ethanol.
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Key Findings & Data:All of these phthalocyanines are soluble in some organic solvents such as DMF, DMSO, THF, CH2Cl2,and CHCl3.
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Conclusion & Impact:The geometricalstructure of two phthalocyanines was investigated at the RHF/3-21G* computational level.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

New thermally stable metallo-phthalocyanines bearing dibenzoxanthenes as highly organo-solubilizing aro-matic hydrocarbon substituents were successfully prepared by cyclotetramerization of corresponding phthalonitriles withanhydrous metal salts [Zn(CH3COO)2and NiCl2] in the presence of a catalytic amount of DBU in 2-(dimethylamino)ethanol. All of these phthalocyanines are soluble in some organic solvents such as DMF, DMSO, THF, CH2Cl2,and CHCl3. Then we successfully prepared the poly(methyl methacrylate) (PMMA)/ZnPc/Al nanocomposite lms byincorporating Al nanoparticles into a transparent PMMA/ZnPc matrix. The structure and morphology of nanocom-posite lms were studied using X-ray diffraction and scanning electron microscopy. The optical absorption spectra ofPMMA/ZnPc/Al nanocomposite lms showed red shifting in the Q-band in the polymeric matrix. The geometricalstructure of two phthalocyanines was investigated at the RHF/3-21G* computational level.

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Cite This Article

KARIMI, A. R., JAFARZADEH, Z., SOURINIA, M., ZENDEHNAM, A., KHODADADI, A., DALIRNASAB, Z., SOLIMANNEJAD, M., ZOLGHARNEIN, P. (2022). Synthesis and computational studies of new metallo-phthalocyanines bearingdibenzoxanthenes and evaluation of their optical properties in solution and solidPMMA/ZnPc/Al nanocomposite films. Turkish Journal of Chemistry, Cilt: 40 - Sayı: 4, 602–612. https://ajindex.com/articles/602065

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References (1)

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