Journals / Turkish Journal of Chemistry / 2019 / Cilt: 43 - Sayı: 5

Electrochemical responses of flexible graphite in H2SO4

Pages
1398–1406
Publication Date
2022-11-04
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The higher positive potential limit in cyclic voltammetry causes peak potential to increase in orders of magnitudes.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:Asymmetric capacitors are gaining attention due to their hybrid nature with higher power and energy densitycompared to individual batteries or capacitors.
📊
Key Findings & Data:Electrochemical and structural characteristics of flexible graphite in 40% H2 SO4 electrolyte are investigated using electrochemical and microscopy techniques.
💡
Conclusion & Impact:The higher positive potential limit in cyclic voltammetry causes peak potential to increase in orders of magnitudes.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

Asymmetric capacitors are gaining attention due to their hybrid nature with higher power and energy densitycompared to individual batteries or capacitors. Electrochemical and structural characteristics of flexible graphite in 40% H2 SO4 electrolyte are investigated using electrochemical and microscopy techniques. There is a correlation between intercalation of electrolyte and the enlargement of interlayer spacing and electrochemical response. Conditions favoring planar orientation are electrochemically less active and more stable in such corrosive electrolytes. There are response variations between plain and resin-impregnated flexible graphite samples. The reaction peak seems to be reversible for resin impregnated samples while plain samples show continuous intercalation. The higher positive potential limit in cyclic voltammetry causes peak potential to increase in orders of magnitudes.

🔖

Cite This Article

YAZICI, M. S. (2022). Electrochemical responses of flexible graphite in H2SO4. Turkish Journal of Chemistry, Cilt: 43 - Sayı: 5, 1398–1406. https://ajindex.com/articles/601903

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (15)

  1. Kinoshita K. Carbon: Electrochemical and Physicochemical Properties. New York, NY, USA: John Wiley & Sons, 1988
  2. Ka BH, Oh SM. Electrochemical activation of expanded graphite electrode for electrochemical capacitor. Journal of the Electrochemical Society 2008; 155 (9): A685-A692
  3. Dhakate SR, Sharma S, Borah M, Mathur RB, Dhami TL. Development and characterization of expanded graphitebased nanocomposite as bipolar plate for polymer electrolyte membrane fuel cells (PEMFCs). Energy & Fuels 2008; 22 (5): 3329-3334
  4. Bhattacharya A, Hazra A, Chatterjee S, Sen P, Laha S et al. Expanded graphite as an electrode material for an alcohol fuel cell. Journal of Power Sources 2004; 136 (2): 208-210
  5. Cao F, Barsukov IV, Bang HJ, Zaleski P, Prakash J. Evaluation of graphite materials as anodes for lithium-ion batteries. Journal of the Electrochemical Society 2000; 147: 3579-3583
  6. Cooper JS. Design analysis of PEMFC bipolar plates considering stack manufacturing and environment impact. Journal of Power Sources 2004; 129: 152-169
  7. Noel M, Santhanam R. Electrochemistry of graphite intercalation compounds. Journal of Power Sources 1998; 72: 53-65
  8. Yazici MS, Krassowski D, Prakash J. Flexible graphite as battery anode and current collector. Journal of Power Sources 2005; 141: 171-176
  9. Ziv B, Haik O, Zinigrad E, Levi MD, Aurbach D et al. Investigation of graphite foil as current collector for positive electrodes of Li-ion batteries. Journal of the Electrochemical Society 2013; 160 (4): A581-A587
  10. Qu H, Hou, J, Tang Y, Semenikhin O, Skorobogatiy M. Thin flexible lithium-ion battery featuring graphite paper based current collectors with enhanced conductivity. Canadian Journal of Chemistry 2017; 95 (2): 169-173
  11. Chung DDL. Flexible graphite for gasketing, adsorption, electromagnetic interference shielding, vibration damping, electrochemical applications, and stress sensing. Journal of Materials Engineering and Performance 2000; 9 (2): 161-163
  12. Mehta V, Cooper JS. Review and analysis of PEM fuel cell design and manufacturing. Journal of Power Sources 2003; 114 (1): 32-53
  13. Middelman E, Kout W, Vogelaar B, Lenssen J, de Waal E. Bipolar plates for PEM fuel cells. Journal of Power Sources 2003; 118 (1-2): 44-46
  14. Dursun B, Yaren F, Unveroglu B, Yazici S, Dundar F. Expanded graphite–epoxy–flexible silica composite bipolar plates for PEM fuel cells. Fuel Cells 2014; 14 (6): 862-867
  15. Yazici MS, Krassowski D, Praksh J. Flexible graphite as