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Journals / Turkish Journal of Chemistry / 2018 / Cilt: 42 - Sayı: 1

Kinetics of silver(I)-catalyzed oxidation of allyl alcohol by peroxodiphosphate in acetate buffers

Priyamvada SHARMA
Riya SAILANI
Deepmala PAREEK
Chandra Lata KHANDELWAL
Pages
158–169
Publication Date
2022-11-05
DOI
—
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AI Summary & Key Takeaways

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⚡ TL;DR(Too Long; Didn't Read)

The energy and entropy of activation have also been evaluated by employing Eyring plots.

📌 3 Key Takeaways

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Objective & Hypothesis:The kinetics and mechanism of silver(I)-catalyzed oxidation of allyl alcohol with peroxodiphosphate in acetate buffers have been studied.
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Key Findings & Data:The rate is independent of allyl alcohol concentration.
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Conclusion & Impact:The energy and entropy of activation have also been evaluated by employing Eyring plots.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

The kinetics and mechanism of silver(I)-catalyzed oxidation of allyl alcohol with peroxodiphosphate in acetate buffers have been studied. The rate is independent of allyl alcohol concentration. The effect of other reaction parameters such as hydrogen and acetate ions has also been studied. The rate law accounting for all experimental observations corresponds to the proposed mechanism. The energy and entropy of activation have also been evaluated by employing Eyring plots.

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Cite This Article

SHARMA, P., SAILANI, R., PAREEK, D., KHANDELWAL, C. L. (2022). Kinetics of silver(I)-catalyzed oxidation of allyl alcohol by peroxodiphosphate in acetate buffers. Turkish Journal of Chemistry, Cilt: 42 - Sayı: 1, 158–169. https://ajindex.com/articles/601780

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