Journals / Turkish Journal of Chemistry / 2018 / Cilt: 42 - Sayı: 5

Poly L-Dopa/poly(ethylenedioxythiophene) as a novel mussel-inspired electroactive binder for environmentally friendly hybrid supercapacitors

Pages
1238–1250
Publication Date
2022-11-01
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Cyclic voltammetry, charge/discharge measurements, and electrochemical impedancespectrometry showed that the hybrid supercapacitors based on Ni-benzidine MOF with the new electroactive binderexhibit very high specific capacitance (770 F $g^{-1}$at 1 A/g) and remarkable capacitance retention of more than 94%after 1000 cycles and 86% after 5000 cycles at high current density of 5 A $g^{-1}$ .

📌 3 Key Takeaways

🎯
Objective & Hypothesis:3,4-Dihydroxy-L-phenylalanine and ethylenedioxythiophene were chemically copolymerized via an oxidativeprocess in aqueous solution.
📊
Key Findings & Data:The binder,in addition to the sticking effect, contributes to electric charge storing via the redox process of catechol moieties ofpoly(3,4-dihydroxy-L-phenylalanine) and also the formation of a high charge-storing double layer due to the presenceof poly(ethylenedioxythiophene).
💡
Conclusion & Impact:Cyclic voltammetry, charge/discharge measurements, and electrochemical impedancespectrometry showed that the hybrid supercapacitors based on Ni-benzidine MOF with the new electroactive binderexhibit very high specific capacitance (770 F $g^{-1}$at 1 A/g) and remarkable capacitance retention of more than 94%after 1000 cycles and 86% after 5000 cycles at high current density of 5 A $g^{-1}$ .
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

3,4-Dihydroxy-L-phenylalanine and ethylenedioxythiophene were chemically copolymerized via an oxidativeprocess in aqueous solution. The copolymer was used as a novel mussel-inspired electroactive binder in conjunctionwith a nickel-based metal organic frame work for fabrication of environmentally friendly supercapacitors. The binder,in addition to the sticking effect, contributes to electric charge storing via the redox process of catechol moieties ofpoly(3,4-dihydroxy-L-phenylalanine) and also the formation of a high charge-storing double layer due to the presenceof poly(ethylenedioxythiophene). Cyclic voltammetry, charge/discharge measurements, and electrochemical impedancespectrometry showed that the hybrid supercapacitors based on Ni-benzidine MOF with the new electroactive binderexhibit very high specific capacitance (770 F $g^{-1}$at 1 A/g) and remarkable capacitance retention of more than 94%after 1000 cycles and 86% after 5000 cycles at high current density of 5 A $g^{-1}$ .

🔖

Cite This Article

HEYDARIPOUR, E., NATEGHI, M. R., MOSSLEMIN, M. H. (2022). Poly L-Dopa/poly(ethylenedioxythiophene) as a novel mussel-inspired electroactive binder for environmentally friendly hybrid supercapacitors. Turkish Journal of Chemistry, Cilt: 42 - Sayı: 5, 1238–1250. https://ajindex.com/articles/601749

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (26)

  1. Zhou, J.; Xiong, Q.; Ma, J.; Ma, J.; Ren, J.; Messersmith, P. B.; Peng Chen, P.; Duan, H. ACS Nano 2016, 10, 11066-11075
  2. Hong, S.; Yang, K.; Kang, B.; Lee, C.; Song, T.; Byun, E.; Park, K.; Cho, S.; Lee, H. Adv. Funct. Mater. 2013, 23, 1774-1780
  3. Zhang, C.; Li, H.; Ping, N.; Pang, G.; Xua, G.; Zhang, X. RSC Adv. 2014, 4, 38791-38796. 4. d’Ischia, M.; Napolitano, A.; Pezzella, A.; Meredith, P.; Sarna, T. Angew. Chem. Int. Ed. 2009, 48, 3914-3921
  4. Dorszewska, J.; Prendecki, M.; Lianeri, M.; Kozubski, W. Curr. Genomics 2014, 15, 11-17
  5. Liu, Y.; Ai, K.; Lu, L. Chem. Rev. 2014, 114, 5057-5115
  6. Mrowczynski, R.; Turcu, R.; Leostean, C.; Scheidt, H. A.; Liebscher, J. Mat. Chem. Phys. 2013, 138, 295-302
  7. Zhang, M.; He, X. W.; Chen, L. X.; Zhang, Y. K. J. Mater. Chem. 2010, 20, 10696-10704
  8. Si, J. Y.; Yang, H. Mat. Chem. Phys. 2011, 128, 519-524
  9. Lee, H.; Dellatore, S. M.; Miller, W. M.; Messersmith, P. B. Science 2007, 318, 426-430
  10. Zhu, L. P.; Yu, J. Z.; Xu, Y. Y.; Xi, Z.; Zhu, B. Colloid. Surface. B 2009, 69, 152-155
  11. Ye, Q.; Zhou, F.; Liu, W. M. Chem. Soc. Rev. 2011, 40, 4244-4258
  12. Fei, B.; Qian, B. T.; Yang, Z. Y.; Wang, R.; Liu, W. C.; Mak, C. L.; Xin, J. H. Carbon 2008, 46, 1795-1797
  13. Xiong, S.; Wang, Y.; Zhu, J.; Yu, J.; Hu, Z. Langmuir 2015, 31, 5504-5512
  14. Yu, L.; Liu, X.; Yuan, W.; Brown, L. J.; Wang, D. Langmuir 2015, 31, 6351-6366
  15. Louwet, F.; Groenendaal, L.; Dhaen, J.; Manca, J.; Van Luppen, J.; Verdonck, E.; Leenders, L. Synth. Met. 2003, 135-136, 115-117
  16. Yin, X.; Wu. F.; Fu, N.; Han, J.; Chen, D.; Xu, P.; He, M.; Lin, Y. ACS Appl. Mater. 2013, 5, 8423-8429
  17. Zhou, H.; Liu, G.; Liu, J.; Wang, Y.; Ai, Q.; Huang, J.; Yuan, Z.; Tan, L.; Chen, Y. Electrochim. Acta 2017, 247, 871-879
  18. Zhao, Z.; Richardson, G. F.; Meng, Q.; Zhu, S.; Kuan, H.; Ma, J. Nanotechnology 2016, 27, 042001
  19. Lee, H.; Yin, J. L.; Park, S. W.; Park, J. Y. Synth. Met. 2017, 228, 84-90
  20. Cha, I.; Lee, E.; Park, H. S.; Kim, J. H.; Kim, Y. H.; Song, C. Synth. Met. 2014, 195, 162-166
  21. Xia, C.; Chen, W.; Wang, X.; Hedhili, M. N.; Wei, N.; Alshareef, H. N. Adv. Energy Mater. 2015, 5, 1401805
  22. Nateghi, M. R.; Savabieh, B. Electrochim. Acta 2014, 121, 128-135
  23. Hakimian, A.; Nateghi, M. R. Synth. Met. 2015, 202, 1-7
  24. Kumar, A.; Singh, R. K.; Singh, H. K.; Srivastava, P.; Singh, R. J. Power Sources 2014, 246, 800-807
  25. Jin, Y.; Deng, D.; Cheng, Y.; Kong, L.; Xiao F. Nanoscale 2014, 6, 4812-4818
  26. Zhang,