Journals / Turkish Journal of Chemistry / 2020 / Cilt: 44 - Sayı: 3

Synthesis and liquid crystalline properties of new triazine-based π-conjugated macromolecules with chiral side groups

Pages
726–735
Publication Date
2022-11-05
DOI
—
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AI Summary & Key Takeaways

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⚡ TL;DR(Too Long; Didn't Read)

The liquid crystalline properties of organic salt were investigated using DSC (differentialscanning calorimetry) and POM (polarizing optical microscopy).

📌 3 Key Takeaways

🎯
Objective & Hypothesis:In this study, we reported the synthesis of a new tribranched macromolecule liquid crystal with triazine in thecentre.
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Key Findings & Data:The central triazine core is bonded via sequences of Sonigashira coupling to 3 triazine unites through acetylenicbridges.
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Conclusion & Impact:The liquid crystalline properties of organic salt were investigated using DSC (differentialscanning calorimetry) and POM (polarizing optical microscopy).
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

In this study, we reported the synthesis of a new tribranched macromolecule liquid crystal with triazine in thecentre. The central triazine core is bonded via sequences of Sonigashira coupling to 3 triazine unites through acetylenicbridges. The triazines at the periphery are substituted with 2 chiral citronellyloxy side groups. The salt of the resultingstar-shaped macromolecule, which was oily at room temperature, with 4-dodecyloxybenzoic acid at 1:1 ratio exhibited aSmectic C (SmC) mesophase. The liquid crystalline properties of organic salt were investigated using DSC (differentialscanning calorimetry) and POM (polarizing optical microscopy).

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Cite This Article

ÇAKAR, F., AKKURT, N., AL-JUMAILI, M. H. A., OCAK, H., TORUN, L. (2022). Synthesis and liquid crystalline properties of new triazine-based π-conjugated macromolecules with chiral side groups. Turkish Journal of Chemistry, Cilt: 44 - Sayı: 3, 726–735. https://ajindex.com/articles/601600

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