Furthermore, the structure of compound 3a was also determined by X-ray crystallography.The thermal behaviors and the spectral properties of the new cyclotriphosphazene compounds (3a–3d) were investigatedand the results were compared in the series.
📌 3 Key Takeaways
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Objective & Hypothesis:In this study, a series of cyclotriphosphazene derivatives containing a Schiff base (3a–3d) were synthesized bythe reactions of hexachlorocyclotriphosphazene (1) with bis-aryl Schiff bases (2a–2d) having different terminal groups(H, F, Cl, and Br).
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Key Findings & Data:The products (3a–3d) were characterized by elemental and mass analyses, FT-IR, and 1 H, 13 C, and31P NMR spectroscopies.
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Conclusion & Impact:Furthermore, the structure of compound 3a was also determined by X-ray crystallography.The thermal behaviors and the spectral properties of the new cyclotriphosphazene compounds (3a–3d) were investigatedand the results were compared in the series.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters
Abstract
In this study, a series of cyclotriphosphazene derivatives containing a Schiff base (3a–3d) were synthesized bythe reactions of hexachlorocyclotriphosphazene (1) with bis-aryl Schiff bases (2a–2d) having different terminal groups(H, F, Cl, and Br). The products (3a–3d) were characterized by elemental and mass analyses, FT-IR, and 1 H, 13 C, and31P NMR spectroscopies. Furthermore, the structure of compound 3a was also determined by X-ray crystallography.The thermal behaviors and the spectral properties of the new cyclotriphosphazene compounds (3a–3d) were investigatedand the results were compared in the series.
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Cite This Article
BALCI, C. M., BEŞLİ, S., TÜMAY, S. O., YEŞİLOT, S., DOĞAN, S. (2022). Synthesis of new cyclotriphosphazene derivatives bearing Schiff bases and their thermal and absorbance properties. Turkish Journal of Chemistry, Cilt: 44 - Sayı: 1, 31–47. https://ajindex.com/articles/601549
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