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Journals / Turkish Journal of Chemistry / 2021 / Cilt: 45 - Sayı: 1

Sensitive determination of hydrazine using poly(phenolphthalein), Au nanoparticles and multiwalled carbon nanotubes modified glassy carbon electrode

Zekerya DURSUN
Müge HATİP
Süleyman KOÇAK
Pages
167–180
Publication Date
2022-11-01
DOI
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

A modified electrode was applied to naturel samples for hydrazine determination.

📌 3 Key Takeaways

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Objective & Hypothesis:This study reports a detailed analysis of an electrode material containing poly(phenolphthalein), carbon nanotubes and gold nanoparticles which shows superior catalytic effect towards to hydrazine oxidation in Britton–Robinson buffer (pH 10.0).
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Key Findings & Data:The peak potential of hydrazine oxidation on bare GCE, poly(PP)/GCE, CNT/GCE, CNT/ poly(PP)/GCE, and AuNPs/CNT/poly(PP)/GCE were observed at 596 mV, 342 mV, 320 mV, 313 mV, and 27 mV, respectively.
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Conclusion & Impact:A modified electrode was applied to naturel samples for hydrazine determination.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

This study reports a detailed analysis of an electrode material containing poly(phenolphthalein), carbon nanotubes and gold nanoparticles which shows superior catalytic effect towards to hydrazine oxidation in Britton–Robinson buffer (pH 10.0). Glassy carbon electrode was modified by electropolymerization of phenolphthalein (PP) monomer (poly(PP)/GCE) and the multiwalled carbon nanotubes (MWCNTs) was dropped on the surface. This modified surface was electrodeposited with gold nanoparticles (AuNPs/CNT/poly(PP)/GCE). The fabricated electrode was analysed the determination of hydrazine using cyclic voltammetry, linear sweep voltammetry and amperometry. The peak potential of hydrazine oxidation on bare GCE, poly(PP)/GCE, CNT/GCE, CNT/ poly(PP)/GCE, and AuNPs/CNT/poly(PP)/GCE were observed at 596 mV, 342 mV, 320 mV, 313 mV, and 27 mV, respectively. A shift in the overpotential to more negative direction and an enhancement in the peak current indicated that the AuNPs/CNT/poly(PP)/GC electrode presented an efficient electrocatalytic activity toward oxidation of hydrazine. Modified electrodes were characterized with High-resolution transmission electron microscopy (HRTEM), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and electrochemical impedance spectroscopy (EIS). Amperometric current responses in the low hydrazine concentration range of 0.25–13 µM at the AuNPs/CNT/poly(PP)/GCE. The limit of detection (LOD) value was obtained to be 0.083 µM. A modified electrode was applied to naturel samples for hydrazine determination.

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Cite This Article

DURSUN, Z., HATİP, M., KOÇAK, S. (2022). Sensitive determination of hydrazine using poly(phenolphthalein), Au nanoparticles and multiwalled carbon nanotubes modified glassy carbon electrode. Turkish Journal of Chemistry, Cilt: 45 - Sayı: 1, 167–180. https://ajindex.com/articles/601504

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