Journals / Turkish Journal of Chemistry / 2021 / Cilt: 45 - Sayı: 4

Preparation and characterization of templated porous carbons from sucrose by one-pot method and application as a $CO_2$ adsorbent

Pages
1257–1269
Publication Date
2022-11-01
DOI
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The templated carbon obtained with the lowest TEOS molar ratio exhibited the highest BET surface area of $1289 m^2 /g$ and micropore volume of $0.467 cm^3 /g$, and showed the highest $CO_2$ uptake of 2.28 mmol/g.

📌 3 Key Takeaways

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Objective & Hypothesis:The templated porous carbons were prepared from sucrose by one-pot method.
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Key Findings & Data:In this method in which the pre-synthesis of the hard template is eliminated, the porous carbons were produced by organic-inorganic self-assembly of sucrose, tetraethyl ortosilicate (TEOS), Pluronic P123 and n-butanol in an acidic medium, and subsequent carbonization.
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Conclusion & Impact:The templated carbon obtained with the lowest TEOS molar ratio exhibited the highest BET surface area of $1289 m^2 /g$ and micropore volume of $0.467 cm^3 /g$, and showed the highest $CO_2$ uptake of 2.28 mmol/g.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

The templated porous carbons were prepared from sucrose by one-pot method. In this method in which the pre-synthesis of the hard template is eliminated, the porous carbons were produced by organic-inorganic self-assembly of sucrose, tetraethyl ortosilicate (TEOS), Pluronic P123 and n-butanol in an acidic medium, and subsequent carbonization. The synthesis parameters such as sucrose amount, TEOS molar ratio and carbonization temperature were evaluated for describing their effects on the pore structures of the synthesized carbons. The prepared porous carbons were characterized by $N_2$adsorption, thermogravimetric analysis (TGA), Raman spectroscopy, X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), and transmission electron microscopy (TEM) techniques. The carbon dioxide adsorption uptakes of the obtained porous carbons were determined at 1 bar and 273 K. The templated carbon obtained with the lowest TEOS molar ratio exhibited the highest BET surface area of $1289 m^2 /g$ and micropore volume of $0.467 cm^3 /g$, and showed the highest $CO_2$ uptake of 2.28 mmol/g.

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Cite This Article

GÜRBÜZ, M., TÜMSEK, F. (2022). Preparation and characterization of templated porous carbons from sucrose by one-pot method and application as a $CO_2$ adsorbent. Turkish Journal of Chemistry, Cilt: 45 - Sayı: 4, 1257–1269. https://ajindex.com/articles/601388

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References (12)

  1. Kaur B, Gupta RK, Bhunia H. Chemically activated nanoporous carbon adsorbents from waste plastic for $CO_2$ capture: breakthrough adsorption study. Microporous and Mesoporous Materials 2019
  2. doi: 10.1016/j.micromeso.2019.03.025 2. Yang G, Song S, Li J, Tang Z, Ye J et al. Preparation and $CO_2$ adsorption properties of porous carbon by hydrothermal carbonization of tree leaves. Journal of Materials Science & Technology 2019
  3. doi: 10.1016/j.jmst.2018.11.019 3. Abd AA, Naji SZ, Hashim AS, Othman MR. Carbon dioxide removal through physical adsorption using carbonaceous and noncarbonaceous adsorbents: a review. Journal of Environmental Chemical Engineering 2020
  4. 104142. doi: 10.1016/j.jece.2020.104142 4. Zhang X, Li W, Lu A. Designed porous carbon materials for efficient $CO_2$ adsorption and separation. New Carbon Materials 2015
  5. 30 (6): 481-501. doi: 10.1016/S1872-5805(15)60203-7 5. Wu X, Zhang C, Tian Z, Cai J. Large-surface-area carbons derived from lotus stem waste for efficient CO2 capture. New Carbon Materials 2018
  6. 33 (3): 252-261. doi: 10.1016/S1872-5805(18)60338-5 6. Zhang W, Bao Y, Bao A. Preparation of nitrogen-doped hierarchical porous carbon materials by a template-free method and application to $CO_2$ capture. Journal of Environmental Chemical Engineering 2020
  7. 103732. doi: 10.1016/j.jece.2020.103732 7. Acar B, Başar MS, Eropak BM, Caglayan BS, Aksoylu AE. $CO_2$ adsorption over modified AC samples: a new methodology for determining selectivity. Catalysis Today 2018
  8. doi: 10.1016/j.cattod.2017.10.011 8. Huang G, Liu Y, Wu X, Cai J. Activated carbons prepared by the KOH activation of a hydrochar from garlic peel and their CO2 adsorption performance. New Carbon Materials 2019
  9. 34 (3): 247-257. doi: 10.1016/S1872-5805(19)60014-4 9. Gouveiaa LGT, Agustini CB, Perez-Lopez OW, Gutterres M. $CO_2$ adsorption using solids with different surface and acid-base properties. Journal of Environmental Chemical Engineering 2020
  10. 103823. doi: 10.1016/j.jece.2020.103823 10. Sibera D, Narkiewicz U, Kapica J, Serafin J, Michalkiewicz B et al. Preparation and characterisation of carbon spheres for carbon dioxide capture. Journal of Porous Materials 2019
  11. doi: 10.1007/s10934-018-0601-8 11. Sun Y, Li K, Zhao J, Wang J, Tang N et al. Nitrogen and sulfur co-doped microporous activated carbon macro-spheres for $CO_2$ capture. Journal of Colloid and Interface Science 2018
  12. doi: 10.1016/j.jcis.20