Journals / Turkish Journal of Chemistry / 2022 / Cilt: 46 - Sayı: 2

Thermodynamic and kinetic study of adsorptive removal of lead by the nanocomposite loaded nanofibers

Pages
342–355
Publication Date
2022-11-01
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Nanocomposites-based adsorbents showed improved adsorption capacity for Pb (II) ions compared to pristine PNF.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:Herein, the fabrication of electrospun nanocomposites, using polyacrylonitrile nanofibers (PNF) modified with nanobentonite and fly ash, is explained.
📊
Key Findings & Data:Further, the use of electrospun adsorbent for the remediation of Pb (II) ions from water has been explored.
💡
Conclusion & Impact:Nanocomposites-based adsorbents showed improved adsorption capacity for Pb (II) ions compared to pristine PNF.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

Herein, the fabrication of electrospun nanocomposites, using polyacrylonitrile nanofibers (PNF) modified with nanobentonite and fly ash, is explained. Further, the use of electrospun adsorbent for the remediation of Pb (II) ions from water has been explored. Pristine PNF and nanocomposites were characterized using SEM, EDX, and FTIR to analyze surface topology, elemental composition, and functional groups, respectively. The adsorptive behavior of developed adsorbents was investigated using the effects of dosage, initial concentration, time, and temperature. Pseudo-second order kinetics fit well with experimental data and the adsorption followed intra-particle diffusion. The thermodynamics study confirmed spontaneous endothermic adsorption of the heavy metal. Nanocomposites-based adsorbents showed improved adsorption capacity for Pb (II) ions compared to pristine PNF.

🔖

Cite This Article

QADIR, B., MAHMOOD, U., ABID, S., NAZIR, A., HUSSAIN, T. (2022). Thermodynamic and kinetic study of adsorptive removal of lead by the nanocomposite loaded nanofibers. Turkish Journal of Chemistry, Cilt: 46 - Sayı: 2, 342–355. https://ajindex.com/articles/601379

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (10)

  1. Zhu F, Zheng YM, Zhang BG, Dai YR. A critical review on the electrospun nanofibrous membranes for the adsorption of heavy metals in water treatment. Journal of Hazardous Materials 2021
  2. 123608. doi: 10.1016/j.jhazmat.2020.123608 2. Yahya MD, Obayomi KS, Abdulkadir MB, Iyaka YA, Olugbenga AG. Characterization of cobalt ferrite-supported activated carbon for removal of chromium and lead ions from tannery wastewater via adsorption equilibrium. Water Science and Engineering 2020
  3. 13 (3): 202–213. doi: 10.1016/j.wse.2020.09.007 3. Hoang MT, Pham TD, Nguyen VT, Nguyen MK, Pham TT et al. Removal and recovery of lead from wastewater using an integrated system of adsorption and crystallization. Journal of Cleaner Production 2019
  4. 1204–1216. doi: 10.1016/j.jclepro.2018.12.275 4. Rashid J, Azam R, Kumar R, Ahmad M, Rehman A et al. Sulfonated polyether sulfone reinforced multiwall carbon nanotubes composite for the removal of lead in wastewater. Applied Nanoscience 2019
  5. 9 (8): 1695–1705. doi: 10.1007/s13204-019-00953-2 5. Chitpong N, Husson SM. High-capacity, nanofiber-based ion-exchange membranes for the selective recovery of heavy metals from impaired waters. Separation and Purification Technology 2017
  6. 94–103. doi: 10.1016/j.seppur.2017.02.009 6. Huang Z, Chen Q, Yao Y, Li X, Lu J et al. Comparison of heavy metal removals from aqueous solutions by chemical precipitation and characteristics of precipitates. Journal of Water Process Engineering 2018
  7. doi: 10.1016/j.jwpe.2018.11.003 7. Tang X, Zheng H, Teng H, Sun Y, Guo J et al. Chemical coagulation process for the removal of heavy metals from water: a review. Desalination and Water Treatment 2016
  8. 57 (4): 1733–1748. doi: 10.1080/19443994.2014.977959 8. Hou T, Du H, Yang Z, Tian Z, Shen S et al. Flocculation of different types of combined contaminants of antibiotics and heavy metals by thermo-responsive flocculants with various architectures. Separation and Purification Technology 2019
  9. 123–132. doi: 10.1016/j. seppur.2019.04.068 9. Sunil K, Karunakaran G, Yadav S, Padaki M, Zadorozhnyy V et al. Al-Ti2O6 a mixed metal oxide based composite membrane: A unique membrane for removal of heavy metals. Chemical Engineering Journal 2018
  10. 678–684. doi: 10.1016/j.cej.2018.05.017 10. Ahmadijokani F, Mohammadkhani R, Ahmadipouya S, Shokrgozar A, Rezakazemi M et al. Superior chemical stability of UiO-66 metalorganic frameworks (MOFs) for selective dye adsorption. Chemical Engineering Jour