Journals / International Journal of Environment and Geoinformatics / 2021 / Cilt: 8 - Sayı: 3

Egg White Cryogel for Removal of Methylene Blue from Aqueous Solution

Pages
328–336
Publication Date
2022-10-19
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

It was found that Langmuir model isotherm provided the best fit with maximum adsorption capacity of 56.18 mg MB/g cryogel.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:Macroporous egg white (EW) cryogel synthesized by cryogelation at sub-zero temperature (-18oC) with crosslinker glutaraldehyde (GA) was tested in the sorption of methylene blue (MB) as a model water pollutant from aqueous solution.
📊
Key Findings & Data:It was found that Langmuir model isotherm provided the best fit with maximum adsorption capacity of 56.18 mg MB/g cryogel.
💡
Conclusion & Impact:Hence, easy preparation, cheapness and good adsorption property make the EW cryogel an economically promising adsorbent for environmental application.
🔬Design:Modeling & Simulation
📍Scope:Comprehensive Sample
⚙️Variables:Cryogel · Biosorbent · Egg White

Abstract

Macroporous egg white (EW) cryogel synthesized by cryogelation at sub-zero temperature (-18oC) with crosslinker glutaraldehyde (GA) was tested in the sorption of methylene blue (MB) as a model water pollutant from aqueous solution. The characterization of obtained cryogel was performed by Fourier-transform infrared spectroscopy and scanning electron microscopy. The pseudo-first order and pseudo-second order models were used to predict the adsorption kinetics. The adsorption followed the pseudo-second order model and experimental adsorption capacity was closer to the calculated one. Two isotherm models called Langmuir and Freundlich were fitted on the experimental data to predict the maximum capacity and process of the adsorption. It was found that Langmuir model isotherm provided the best fit with maximum adsorption capacity of 56.18 mg MB/g cryogel. The dyed EW cryogel was easily regenerated and used several times with no noticeable reduction of capacity. The electrostatic attraction was the main adsorption mechanism of MB on the cryogel, especially at slightly basic pH. Hence, easy preparation, cheapness and good adsorption property make the EW cryogel an economically promising adsorbent for environmental application.

🔖

Cite This Article

GÜLYÜZ, Ü. (2022). Egg White Cryogel for Removal of Methylene Blue from Aqueous Solution. International Journal of Environment and Geoinformatics, Cilt: 8 - Sayı: 3, 328–336. https://ajindex.com/articles/540904

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (12)

  1. Balaji, P., Murugadas, A., Shanmugaapriya, S., & Akbarsha, M. A. (2019). Fabrication and characterization of egg white cryogel scaffold for three-dimensional (3D) cell culture. Biocatalysis and Agricultural Biotechnology, 17, 441-446.
  2. Bayramoglu, G., Altintas, B., & Arica, M. Y. (2009). Adsorption kinetics and thermodynamic parameters of cationic dyes from aqueous solutions by using a new strong cation-exchange resin. Chemical Engineering Journal, 152(2-3), 339-346.
  3. Bolto, B., & Gregory, J. (2007). Organic polyelectrolytes in water treatment. Water research, 41(11), 2301-2324.
  4. Crini, G. (2006). Non-conventional low-cost adsorbents for dye removal: a review. Bioresource technology, 97(9), 1061-1085.
  5. Crini, G., & Badot, P.-M. (2008). Application of chitosan, a natural aminopolysaccharide, for dye removal from aqueous solutions by adsorption processes using batch studies: A review of recent literature. Progress in Polymer Science, 33(4), 399-447.
  6. Croguennec, T., Nau, F., Pezennec, S., & Brule, G. (2000). Simple rapid procedure for preparation of large quantities of ovalbumin. Journal of Agricultural and Food Chemistry, 48(10), 4883-4889.
  7. Dalaran, M., Emik, S., Güçlü, G., İyim, T. B., & Özgümüş, S. (2011). Study on a novel polyampholyte nanocomposite superabsorbent hydrogels: Synthesis, characterization and investigation of removal of indigo carmine from aqueous solution. Desalination, 279(1), 170-182.
  8. Dinu, M. V., Ozmen, M. M., Dragan, E. S., & Okay, O. (2007). Freezing as a path to build macroporous structures: superfast responsive polyacrylamide hydrogels. Polymer, 48(1), 195-204.
  9. Dinu, M. V., Perju, M. M., & Drăgan, E. S. (2011). Porous Semi-Interpenetrating Hydrogel Networks Based on Dextran and Polyacrylamide With Superfast Responsiveness. Macromolecular Chemistry and Physics, 212(3), 240-251.
  10. Doğan, M., Abak, H., & Alkan, M. (2009). Adsorption of methylene blue onto hazelnut shell: kinetics, mechanism and activation parameters. Journal of Hazardous Materials, 164(1), 172-181.
  11. Dragan, E. S., & Loghin, D. F. A. (2013). Enhanced sorption of methylene blue from aqueous solutions by semi-IPN composite cryogels with anionically modified potato starch entrapped in PAAm matrix. Chemical Engineering Journal, 234, 211-222.
  12. Erdem, A., Ngwabebhoh, F. A., & Yildiz, U. (2017). Novel macroporous cryogels with enhanced adsorption capability for the removal of Cu(II) ions from aqueous phase: Modelling, kinetics and recovery studies. Journal of Environmental Chemical Eng