Journals / European Mechanical Science / 2022 / Cilt: 6 - Sayı: 3

Comparison of pure-hydrogen production performances of blast furnace slag, and metal powders in sodium borohydride hydrolysis reaction

Pages
179–188
Publication Date
2022-10-12
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Among the Fe2O3 catalyst samples, the highest efficiency performances are achieved with Fe2O3 Nano catalyst samples at 50 °C preheat with an instantaneous hydrogen generation rate of approximately 29.91 L / min for 12 minutes.

📌 3 Key Takeaways

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Objective & Hypothesis:In this study, hydrolysis reaction performances of raw BFS powder and metal powders (which are ingredients of BFS) that are using as a catalyst are compared.
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Key Findings & Data:Hydrogen generation by hydrolysis reaction of the Al and Fe2O3 Nano & Granule powders with sodium borohydride (NaBH4) addition in water was studied by using different catalysts amount at reaction vessels.
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Conclusion & Impact:Among the Fe2O3 catalyst samples, the highest efficiency performances are achieved with Fe2O3 Nano catalyst samples at 50 °C preheat with an instantaneous hydrogen generation rate of approximately 29.91 L / min for 12 minutes.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Metal powders · NaBH4 · Hydrogen production

Abstract

In this study, hydrolysis reaction performances of raw BFS powder and metal powders (which are ingredients of BFS) that are using as a catalyst are compared. Hydrogen generation by hydrolysis reaction of the Al and Fe2O3 Nano & Granule powders with sodium borohydride (NaBH4) addition in water was studied by using different catalysts amount at reaction vessels. The measured values of reaction temperatures and hydrogen flow rates were measured by using high-precision equipment. As a result of the obtained data, it was determined that Fe2O3 and Al catalysts have advantages over hydrogen production rate and fuel conversion, also, these experiments show a very high success in different parameters, and create promising effects in the reactions. Among the Al catalyst samples, the highest efficiency performances are achieved with Al Nano catalyst samples at 85.31 °C preheat with an instantaneous hydrogen generation rate of approximately 11.226 L / min for 33 minutes. Among the Fe2O3 catalyst samples, the highest efficiency performances are achieved with Fe2O3 Nano catalyst samples at 50 °C preheat with an instantaneous hydrogen generation rate of approximately 29.91 L / min for 12 minutes.

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Cite This Article

BALTACIOĞLU, M. K., İSKENDEROĞLU, F. C. (2022). Comparison of pure-hydrogen production performances of blast furnace slag, and metal powders in sodium borohydride hydrolysis reaction. European Mechanical Science, Cilt: 6 - Sayı: 3, 179–188. https://ajindex.com/articles/512387

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References (10)

  1. Barbir, F., Veziroǧlu, T.N., Plass, H.J., (1990). Environmental damage due to fossil fuels use. International Journal of Hydrogen Energy. doi: 10.1016/0360-3199(90)90005-J
  2. Panwar, N.L., Kaushik, S.C., Kothari, S., (2011). Role of renewable energy sources in environmental protection: A review. Renewable and Sustainable Energy Reviews. doi: 10.1016/j.rser.2010.11.037
  3. Yang, H., Lombardo, L., Luo, W., Kim, W., Züttel, A., (2018). Hydrogen storage properties of various carbon supported NaBH4 prepared via metathesis. International Journal of Hydrogen Energy. doi: 10.1016/j.ijhydene.2018.02.142
  4. Nabid, M.R., Bide, Y., Kamali, B., (2019). Hydrogen release from sodium borohydride by Fe2O3@nitrogen-doped carbon core-shell nanosheets as reasonable heterogeneous catalyst. International Journal of Hydrogen Energy. doi: 10.1016/j.ijhydene.2019.08.038
  5. Balbay, A., Selvi̇tepe, N., Saka, C., (2021). Fe doped-CoB catalysts with phosphoric acid-activated montmorillonite as support for efficient hydrogen production via NaBH4 hydrolysis. International Journal of Hydrogen Energy. doi: 10.1016/j.ijhydene.2020.09.181
  6. Schlesinger, H.I., Brown, H.C., Finholt, A.E., Gilbreath, J.R., Hoekstra, H.R., Hyde, E.K., (1953). Sodium Borohydride, Its Hydrolysis and its Use as a Reducing Agent and in the Generation of Hydrogen. Journal of the American Chemical Society. doi: 10.1021/ja01097a057
  7. Lee, J., Shin, H., Choi, K.S., Lee, J., Choi, J.Y., Yu, H.K., (2019). Carbon layer supported nickel catalyst for sodium borohydride (NaBH4) dehydrogenation. International Journal of Hydrogen Energy. doi: 10.1016/j.ijhydene.2018.11.218
  8. Baydaroglu, F., Özdemir, E., Hasimoglu, A., (2014). An effective synthesis route for improving the catalytic activity of carbon-supported Co-B catalyst for hydrogen generation through hydrolysis of NaBH4. International Journal of Hydrogen Energy. doi: 10.1016/j.ijhydene.2013.04.111
  9. Wei, Y., Wang, Y., Wei, L., Zhao, X., Zhou, X., Liu, H., (2018). Highly efficient and reactivated electrocatalyst of ruthenium electrodeposited on nickel foam for hydrogen evolution from NaBH4 alkaline solution. International Journal of Hydrogen Energy. 43(2): 592–600. doi: 10.1016/j.ijhydene.2017.11.010
  10. Dai, P., Zhao, X., Xu, D., Wang, C., Tao, X., Liu, X., et al., (2019). Preparation, characterization, and properties of Pt/Al2O3/cordierite monolith catalyst for hydrogen generation from hydrolysis of sodium borohydride in a flow reactor. Internati