Journals / Ekoloji / 2010 / Cilt: 19 - Sayı: 77

Petrokimya endüstrisi atıksularının Box-Wilson deneysel tasarım metodu kullanılarak güneş ışığı oksidasyonu prosesi ile arıtmı

Treatment of a petrochemical Industry wastewater by a solar oxidation process using The Box-Wilson experimental design method

Journal
Ekoloji
Pages
9–15
Publication Date
2022-10-17
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The maximum reduction in the TOC concentration was 49% with the addition of 2677 mg/L $H _2O _2$ and 0.5mM Fe(III) at a 10 L/h flowrate after 8 hours of exposure to solar irradiation.

📌 3 Key Takeaways

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Objective & Hypothesis:As an advanced oxidation treatment, the Fe(III)/ $H _2O _2$/Solar-UV process was applied to a petrochemical refinery wastewater in Izmir, Turkey.
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Key Findings & Data:The Box-Wilson experimental design method was employed to optimize the wastewater flowrate, oxidant and catalyst concentrations as significant factors for maximum organic matter removal.
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Conclusion & Impact:The maximum reduction in the TOC concentration was 49% with the addition of 2677 mg/L $H _2O _2$ and 0.5mM Fe(III) at a 10 L/h flowrate after 8 hours of exposure to solar irradiation.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

As an advanced oxidation treatment, the Fe(III)/ $H _2O _2$/Solar-UV process was applied to a petrochemical refinery wastewater in Izmir, Turkey. A solar photocatalytic reactor was used for the advanced oxidation. The Box-Wilson experimental design method was employed to optimize the wastewater flowrate, oxidant and catalyst concentrations as significant factors for maximum organic matter removal. Organic matter removal was monitored throughout the operation period. The maximum reduction in the TOC concentration was 49% with the addition of 2677 mg/L $H _2O _2$ and 0.5mM Fe(III) at a 10 L/h flowrate after 8 hours of exposure to solar irradiation.

Özet

İzmir'de (Türkiye) bulunan bir petrokimya rafineri atıksuyuna ileri oksidasyon yöntemlerinden biri olan Fe(III)/ $H _2O _2$/Solar-UV prosesi uygulanmıştır. İleri oksidasyon için bir güneş enerjisi fotokatalitik reaktörü kullanılmıştır. Organik madde giderimi üzerine en önemli etkileri olan atıksu debisi, oksidant madde ve katalist konsatrastonunu optime etmek için Box-Wilson deneysel tasarım metodu uygulanmıştır. Organik madde giderimi deney süresince gözlenmiştir. Maksimum TOK giderimi (%49), 2677 mg/L $H _2O _2$ ve 0,5 mM Fe(III) 10 L/s debide 8 saat güneş ışığı oksidasyonu sonunda elde edilmiştir.

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Cite This Article

PARILTI, N. B. (2022). Petrokimya endüstrisi atıksularının Box-Wilson deneysel tasarım metodu kullanılarak güneş ışığı oksidasyonu prosesi ile arıtmı. Ekoloji, Cilt: 19 - Sayı: 77, 9–15. https://ajindex.com/articles/499106

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References (13)

  1. Alhakimi G, Studnicki LH, Al-Ghazali M (2003) Photocatalytic destruction of potassium hydrogen phthalate using TiO2 and sunlight: application for the treatment of industrial wastewater. Journal of Photochemistry and Photobiology A: Chemistry 154, 219-228.
  2. Amat AM, Arques A, L´opez F, Miranda MA (2005) Solar photo-catalysis to remove paper mill wastewater pollutants. Solar Energy 79, 393-401.
  3. Anonymous (2005) Standart Methods for the Examination of Water and Wastewater. APHA, AWWA, WEF, Washington DC. Bali U (2004) Application of Box-Wilson experimental design method for the photodegradation of textile dyestuff with UV/H2O2 process. Dyes and Pigments 60, 187-195.
  4. Bossmann SH, Oliveros E, Gob S, Siegwart S, Dahlen EP, Payawan LJ, Straub M, Worner M, Braun AM (1998) New evidence against hydroxyl radicals as reactive intermediates in the thermal and photochemically enhanced Fenton reactions. Journal of Physical Chemistry A 102, 5542-5550.
  5. Coelho A, Castro AV, Dezotti M, Sant'Anna Jr. GL (2006) Treatment of petroleum refinery sourwater by advanced oxidation processes. Journal of Hazardous Materials B 137, 178-184.
  6. Daneshvar N, Rabbani M, Modirshahla N, Behnajady MA (2005) Photooxidative degradation of Acid Red 27 in a tubular continuous-flow photoreactor: influence of operational parameters and mineralization products. Journal of Hazardous Materials 118, 155-160.
  7. Demirci S, Erdogan BR (1998) Wastewater treatment at the petroleum refinery, Kirikkale, Turkey using some coagulants and Turkish clays as coagulant aids. Water Research 32, 3495-3499.
  8. Elmaleh S, Ghaffor N (1996) Upgrading oil refinery effluents by cross flow ultrafiltration. Water Science and Technology 34, 231-238.
  9. Fica-Piras P (2000) Refinery Effluent Nitrification Studies in Triphasic Bioreactors. MSc Thesis (in Portuguese), Federal University of Rio de Janeiro, Rio de Janeiro. Gogate PR, Pandit AB (2004) A review of imperative technologies for wastewater treatment. I. Oxidation technologies at ambient conditions. Advanced Environment Research 8, 501-551.
  10. Koh SM, Dixon JB (2001) Preparation and application of organo-minerals as sorbents of phenol, benzene and toluene. Applied Clay Science 18, 111-122.
  11. Leiknes T, Semmens MJ (2000) Membrane filtration for preferential removal of emulsified oil from water. Water Science and Technology 41, 101-108.
  12. Malato S, Blanco J, Vidal A (2002) New large solar photocatalytic plant: set-up and preliminary results. Chemosphere 47, 235-240.
  13. Perez M, Torrades F, Garcia