Journals / Düzce Üniversitesi Bilim ve Teknoloji Dergisi / 2018 / Cilt: 6 - Sayı: 1

Effect of ultraviolet stabilizers on rubber-based automotive sealing profiles

Ultraviyole stabilizatörlerin kauçuk esaslı otomotiv sızdırmazlık profilleri üzerindeki etkisi

Pages
240–253
Publication Date
2022-10-12
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The effects of the UV stabilizers on the EPDM plates were measured by mechanical tests and the internationally recognized Florida outdoor aging test with climate conditions of high-intensity sunlight, high-intensity UV, and high temperature and humidity levels.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:The sealing profiles for many visible and invisible automotive applications such as doors, windows, hoods and trunks are made of synthetic ethylene propylene diene monomer (EPDM) rubber.
📊
Key Findings & Data:This combination of ethylene, propylene and unsaturated diene molecules exhibits high mechanical properties and forms a water-proof structure.
💡
Conclusion & Impact:The effects of the UV stabilizers on the EPDM plates were measured by mechanical tests and the internationally recognized Florida outdoor aging test with climate conditions of high-intensity sunlight, high-intensity UV, and high temperature and humidity levels.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:EPDM · UV Stabilizatörler · EPDM

Abstract

The sealing profiles for many visible and invisible automotive applications such as doors, windows, hoods and trunks are made of synthetic ethylene propylene diene monomer (EPDM) rubber. This combination of ethylene, propylene and unsaturated diene molecules exhibits high mechanical properties and forms a water-proof structure. With the progress of time, color change, cracking and staining can be observed on the surface of the sealing profiles used on the visible regions exposed to the sun due to the effect of high-intensity ultraviolet (UV) radiation and sunlight. The aim of this study was to investigate the effect of the UV stabilizers widely used in the plastics industry on the UV resistance of EPDM rubber. UV stabilizers protect the polymers against to UV radiation by reacting with the free radicals that are formed when a high energy UV photon causes a chemical bond in the polymer to break or by absorbing potentially destructive UV radiation. Plates of EPDM rubber were prepared by adding different types of UV stabilizers at different rates to an available EPDM formula. The effects of the UV stabilizers on the EPDM plates were measured by mechanical tests and the internationally recognized Florida outdoor aging test with climate conditions of high-intensity sunlight, high-intensity UV, and high temperature and humidity levels.

Özet

Kapı, cam, kaput ve bagaj gibi aracın görünür ve görünmez birçok bölgesinde kullanılan sızdırmazlık profilleri; sentetik etilen propilen dien monomer (EPDM) kauçuktan üretilmektedir. Etilen, propilen ve doymamış dien moleküllerinin bu kombinasyonu, yüksek mekanik özellikler sergiler ve su geçirmez bir yapı oluşturur. Güneş ışığına maruz kalan görünür bölgede kullanılan sızdırmaz profillerin yüzeyinde, yüksek yoğunluklu ultraviyole (UV) radyasyonun ve güneş ışığının etkisiyle, zamanla renk değişimi, çatlama ve lekelenme gözlemlenebilir. Bu çalışmanın amacı, plastik endüstrisinde yaygın olarak kullanılan UV stabilizatörlerin EPDM kauçuğunun UV dayanımına olan etkisini araştırmaktır. UV stabilizatörleri, polimerde meydana gelen kimyasal bağ kırılımı nedeni ile oluşan serbest radikaller ile tepkimeye girerek veya UV ışımayı absorbe ederek polimeri UV ışınlarına karşı korur. Mevcut EPDM formülasyonuna farklı tip ve farklı oranlarda UV stabilizatörler eklenerek EPDM hamur plakaları oluşturulmuştur. UV stabilizatörlerin EPDM plakaları üzerindeki etkileri; mekanik testler ve yüksek yoğunluklu güneş ışığı, yüksek yoğunluklu UV ile yüksek sıcaklık/nem içeren iklim koşullarına sahip ve uluslararası alanda tanınmış Florida açık hava yaşlanma testi ile ölçülmüştür.

🔖

Cite This Article

GERENGİ, H., GÜNER, Y., KUCUK, S. D. (2022). Effect of ultraviolet stabilizers on rubber-based automotive sealing profiles. Düzce Üniversitesi Bilim ve Teknoloji Dergisi, Cilt: 6 - Sayı: 1, 240–253. https://ajindex.com/articles/494528

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (12)

  1. Teisseidre G, Pilichowski JF, Chmela S, Lacoste J, “Ageing of epdm- i: Photo and thermal stability of epdm hydroperoxides,” Polym Degrad Stab, vol. 53, no. 2, pp. 207-215, 1996
  2. Alagar M, Abdul Majeed SM, Selvaganapathi A, Gnanasundaram P, “Studies on thermal, thermal aging and morphological characteristics of EPDM-g-VTES/LLDPE,” Eur Polym J, vol. 42, no. 2, pp. 336-347, 2006
  3. Yu L, Wang WJ, Xiao WD, “The effect of decabromodiphenyl oxide and antimony trioxide on the flame retardation of ethylene-propylene-diene copolymer/polypropylene blends,” Polym Degrad Stab, vol. 86, no. 1, pp. 69-73, 2004
  4. Pinel B, Boutand F, “A methodology to predict the life duration of polymers used in nuclear power stations. Industrial needs and their approach,” Nucl Instrum Methods Phys Res Sect B, vol. 151, no. 1-4, pp. 471-476, 1999
  5. Vieira I, Severgnini VLS, Mazera DJ, Soldi MS, Pinheiro EA, Pires ATN, “Effects of maleated ethylene propylene diene rubber (EPDM) on the thermal stability of pure polyamides, and polyamide/EPDM and polyamide/poly(ethylene teraphthalate) blends: kinetic parameters and reaction mechanism,” Polym Degrad Stab, vol. 74, no. 1, pp. 151-157, 2001
  6. Tillier DL, Mesldijk J, Hohne G, Frederik PM, Regev O, Koning CE, “About morphology in ethylene-propylene(-diene) copolymers-based latexes,” Polymer, vol. 46, no. 18, pp. 7094-7108, 2005
  7. Bhadane PA, Champagne MF, Huneault MA, Tofan F, Favis BD, “Continuity development in polymer blends of very low interfacial tension,” Polymer, vol. 47, no. 8, pp. 2760- 2771, 2006
  8. Acharya H, Pramanik M, Srivastava SK, Bhowmick AK, “Synthesis and evaluation of high-performance ethylene–propylene–diene terpolymer/organoclay nanoscale composites,” J Appl Polym Sci, vol. 93, no. 5, pp. 2429-2436, 2004
  9. Valentini L, Biagiotti J, Kenny JM, Manchade MAL, “Physical and mechanical behavior of single walled carbon nanotube/polypropylene/ethylene–propylene–diene rubber nanocomposites,” J Appl Polym Sci, vol. 89, no. 10, pp. 2657-2663, 2003
  10. Wang Y, Zhang L, Tang C, Yu D, “Preparation and characterization of rubber-clay nanocomposites,” J Appl Polym Sci, vol. 78, no. 11, pp. 1879-1883, 2000
  11. Arroyo M, Lopez-Manchado MA, Herrero B, “Organo-montmorillonite as substitute of carbon black in natural rubber compounds,” Polymer, vol. 44, no. 8, pp. 2447-2453, 2003
  12. Goncalves Costa V, Celia Reis Nunes R, “Mechanical properties of blends of EPDM with NR-cellulose II system,” Eur Polym J, vol. 30