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Journals / Düzce Üniversitesi Bilim ve Teknoloji Dergisi / 2018 / Cilt: 6 - Sayı: 4

Investigation of Fluorescence Properties of Bis-N,N'(Salycylidene)- 1,4-Butanediamine Towards Various Metals

Bis-N,N'(Salisiliden)-1,4-Bütandiaminin Çeşitli Metallere Karşı Gösterdiği Floresans Özelliklerinin İncelenmesi

Hanife SEZER
Ümit ERGUN
Ece ERGUN
Pages
1163–1177
Publication Date
2022-10-12
DOI
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The studies related to the effect of other metal ions on the fluorescence properties of ligand+Zn and ligand+Al mixtures demonstrated that Al3+, Cu2+, Fe3+ and Cr3+ interfered with Zn2+ dedection, whereas Hg2+, Fe3+ ve Cu2+ showed interference in the determination of Al3+ ions.

📌 3 Key Takeaways

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Objective & Hypothesis:In this study, a Schiff base compound bis-N,N'(salicylidene)-1,4-butanediamine was synthesized and its fluorescence sensitivity to various metal ions in ethanol:water mixture was investigated.
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Key Findings & Data:Schiff base sensor showed selective fluorescent enhancement towards Zn2+ and Al3+ ions at different excitation and emission wavelengths.
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Conclusion & Impact:The studies related to the effect of other metal ions on the fluorescence properties of ligand+Zn and ligand+Al mixtures demonstrated that Al3+, Cu2+, Fe3+ and Cr3+ interfered with Zn2+ dedection, whereas Hg2+, Fe3+ ve Cu2+ showed interference in the determination of Al3+ ions.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

In this study, a Schiff base compound bis-N,N'(salicylidene)-1,4-butanediamine was synthesized and its fluorescence sensitivity to various metal ions in ethanol:water mixture was investigated. Schiff base sensor showed selective fluorescent enhancement towards Zn2+ and Al3+ ions at different excitation and emission wavelengths. The similar fluorescent emission behaviours for the ligand+metal mixtures have also been detected under the UV light. Additionally, the parameters such as solvent effect, optimum ligand concentration and fluorescence time of response have also been determined. The studies related to the effect of other metal ions on the fluorescence properties of ligand+Zn and ligand+Al mixtures demonstrated that Al3+, Cu2+, Fe3+ and Cr3+ interfered with Zn2+ dedection, whereas Hg2+, Fe3+ ve Cu2+ showed interference in the determination of Al3+ ions.

Özet

Bu çalışmada bis-N,N'(salisiliden)-1,4-bütandiamin Schiff bazı sentezlenmiş ve etanol:su karışımında çeşitlimetal iyonlarına karşı floresans duyarlılığı araştırılmıştır. Schiff bazı sensörü farklı uyarma ve emisyon dalgaboylarında Zn2+ ve Al3+ iyonlarına karşı seçici floresans özelliği göstermiştir. Ligand+metal karışımları içinbenzer floresans davranışları UV lamba altında da gözlenmiştir. Buna ek olarak, çözücü etkisi, optimum ligandkonsantrasyonu ve floresans cevap zamanları gibi parametreler de belirlenmiştir. Ligand+Zn ve ligand+Alkarışımlarının floresans özellikleri üzerine diğer metal iyonlarının etkisi ile ilgili olan çalışmalar ile Al3+, Cu2+,Fe3+ ve Cr3+ iyonlarının Zn2+ iyonunun; Hg2+, Fe3+ ve Cu2+ iyonlarının ise Al3+ iyonunun belirlenmesinde girişimetkisi gösterdiği tespit edilmiştir.

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Cite This Article

SEZER, H., ERGUN, Ü., ERGUN, E. (2022). Investigation of Fluorescence Properties of Bis-N,N'(Salycylidene)- 1,4-Butanediamine Towards Various Metals. Düzce Üniversitesi Bilim ve Teknoloji Dergisi, Cilt: 6 - Sayı: 4, 1163–1177. https://ajindex.com/articles/494499

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