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Journals / Düzce Üniversitesi Bilim ve Teknoloji Dergisi / 2019 / Cilt: 7 - Sayı: 3

Synthesis and Determination of Thermal Decomposition of Biological Active Arene Ruthenium Compound Containing Bisbenzimidazole Linker

Bisbenzimidazol Bağlayıcı İçeren Biyolojik Aktif Aren Rutenyum Bileşiğinin Sentezi ve Termal Bozunmasının Belirlenmesi

Nilüfer ÖKSÜZ
Ersin ORHAN
Pages
1899–1908
Publication Date
2022-10-12
DOI
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

These measurements were made by Thermogravimetric analysis (TGA) and Differential thermal analysis (DTA) techniques.

📌 3 Key Takeaways

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Objective & Hypothesis:In this study, [Ru4(p-cymene)4(μ-NՈN)2(μ4-OOՈOO)2][CF3SO3)4] (NՈN = Butylene-1,4-bisbenzimidazole (bbim)) biologically active tetranuclear arene complex compound, reacting Ru2(p-cymene)2(μ4- OOՈOO) Cl2 (OOՈOO = 5,8-dioxido-1,4-naphtoquinonato (donq)) with silver trifluoromethanesulfonate, followed by the addition of the corresponding NՈN linkers.
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Key Findings & Data:The biologically active arene ruthenium compound was characterized by standard techniques including IR, UV-VIS, 1H NMR, 13C NMR spectroscopy and ESI-MS spectrometry.
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Conclusion & Impact:These measurements were made by Thermogravimetric analysis (TGA) and Differential thermal analysis (DTA) techniques.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Aren rutenyum · Bisbenzimidazol · Supramoleküler kimya

Abstract

In this study, [Ru4(p-cymene)4(μ-NՈN)2(μ4-OOՈOO)2][CF3SO3)4] (NՈN = Butylene-1,4-bisbenzimidazole (bbim)) biologically active tetranuclear arene complex compound, reacting Ru2(p-cymene)2(μ4- OOՈOO) Cl2 (OOՈOO = 5,8-dioxido-1,4-naphtoquinonato (donq)) with silver trifluoromethanesulfonate, followed by the addition of the corresponding NՈN linkers. The biologically active arene ruthenium compound was characterized by standard techniques including IR, UV-VIS, 1H NMR, 13C NMR spectroscopy and ESI-MS spectrometry. Thermal decomposition measurement data of arene ruthenium compound were examined. These measurements were made by Thermogravimetric analysis (TGA) and Differential thermal analysis (DTA) techniques.

Özet

Bu çalışmada [Ru4(p-cymene)4(μ2-NՈN)2(μ4-OOՈOO)2][CF3SO3)4] (NՈN = Bütilen-1,4-bisbenzimidazol (bbim)) genel formülüne sahip biyolojik aktif tetranükleer aren rutenyum kompleks bileşiği, Ru2(p-cymene)2 (μ4-OOՈOO)Cl2 (OOՈOO = 5,8-dioxido-1,4-naphtoquinonato (donq))'nun gümüş triflorometansülfonat ile reaksiyona sokulması, ardından karşılık gelen NՈN bağlayıcılarının eklenmesi ile hazırlanmıştır. Biyolojik aktif aren rutenyum bileşiği IR, UV-VIS, 1H, 13C NMR spektroskopisi ve ESI-MS spektrometresi dahil standart tekniklerle karakterize edildi. Aren rutenyum bileşiğinin termal bozunma ölçüm verileri incelendi. Bu ölçümler Termogravimetrik analiz (TGA) ve Diferansiyel termal analiz (DTA) teknikleri ile yapıldı.

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Cite This Article

ÖKSÜZ, N., ORHAN, E. (2022). Synthesis and Determination of Thermal Decomposition of Biological Active Arene Ruthenium Compound Containing Bisbenzimidazole Linker. Düzce Üniversitesi Bilim ve Teknoloji Dergisi, Cilt: 7 - Sayı: 3, 1899–1908. https://ajindex.com/articles/494312

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