The spectral features suggested that these compounds were similar in structure to the Hofmann-Td-type clathrates.
📌 3 Key Takeaways
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Objective & Hypothesis:Mn(DMPDA)M(CN).2C6H6Cd(DMPDA)M(CN)4.C6H6 (M= Cd or Hg) Hofmann-Td-type clathrates were synthesized and characterized by vibrational spectroscopy.
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Key Findings & Data:Infrared spectra of Mn(DMPDA)M(CN)4.2C6H6 (M = Cd, Hg or Zn; DMPDA = 2,2-dimethyl-1,3diaminopropane), the vibrational spectra of Cd(DMPDA)M(CN)4.C6H6 (M= Cd or Hg) were reported.
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Conclusion & Impact:The spectral features suggested that these compounds were similar in structure to the Hofmann-Td-type clathrates.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters
Abstract
Mn(DMPDA)M(CN).2C6H6Cd(DMPDA)M(CN)4.C6H6 (M= Cd or Hg) Hofmann-Td-type clathrates were synthesized and characterized by vibrational spectroscopy. Infrared spectra of Mn(DMPDA)M(CN)4.2C6H6 (M = Cd, Hg or Zn; DMPDA = 2,2-dimethyl-1,3diaminopropane), the vibrational spectra of Cd(DMPDA)M(CN)4.C6H6 (M= Cd or Hg) were reported. All the vibrational modes of coordinated DMPDA were characterised. The spectral features suggested that these compounds were similar in structure to the Hofmann-Td-type clathrates.
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Cite This Article
AYDIN, T. A. (2022). SYNTHESIS AND CHARACTERIZATION OF THE Td-TYPE CLATHRATES: M(2,2- DIMETHYL-1,3-DIAMINOPROPANE)M'(CN)4.2C6H6 (M= Mn or Cd, M'= Cd, Hg or Zn). Anadolu Üniversitesi Bilim ve Teknoloji Dergisi :A-Uygulamalı Bilimler ve Mühendislik, Cilt: 18 - Sayı: 1, 139–145. https://ajindex.com/articles/438493
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