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Journals / Anadolu Üniversitesi Bilim ve Teknoloji Dergisi :A-Uygulamalı Bilimler ve Mühendislik / 2006 / Cilt: 7 - Sayı: 1

The organic solvent and acid effect on the electro-reduction reaction of the 4-nitroso-N,N-dimetilaniline on graphite electrode

4-nitrozo-N, N-dimetilanilinin grafit elektrot üzerindeki elektro-indirgenme reaksiyonu üzerine organik çözücü ve asit etkisi

A. Tarık PEKEL
Kamran POLAT
Pages
195–204
Publication Date
2022-10-11
DOI
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

A mechanism on the electro-reduction process with respect to the result obtained has been suggested.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:In this study, the electro-reduction reaction of 4-nitroso-N,N-dimethylaniline to 4-amino-N,N- dimethylaniline in a aqueous acidic media containing organic solvents on graphite electrode has been studied with cyclic voltammetric methods.
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Key Findings & Data:Best results were obtained in 10% MeOH containing 1 M H2SO4.
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Conclusion & Impact:A mechanism on the electro-reduction process with respect to the result obtained has been suggested.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

In this study, the electro-reduction reaction of 4-nitroso-N,N-dimethylaniline to 4-amino-N,N- dimethylaniline in a aqueous acidic media containing organic solvents on graphite electrode has been studied with cyclic voltammetric methods. Parameters such as organic solvent, supporting electrolyte and concentration effect on the reduction mechanism have been investigated and optimized. Best results were obtained in 10% MeOH containing 1 M H2SO4. A mechanism on the electro-reduction process with respect to the result obtained has been suggested.

Özet

Bu çalışmada, 4-nitrozo-N,N-dimetilanilinin grafit elektrot üzerinde, organik çözücü içeren sulu asitli ortamda, 4-amino-N,N-dimetilaniline elektro-indirgenme reaksiyonu dönüşümlü voltametri yöntemiyle incelenmiştir. Organik çözücü ile destek elektroliti olarak kullanılacak uygun asit ve derişimi gibi değişkenlerin elektro-indirgenme reaksiyonunun yürüyüşüne etkisi araştırılmış, optimum koşullar belirlenmeye çalışılmıştır. En iyi sonuç, %10 MeOH içeren 1 M H2SO4 içinde elde edilmiştir. Ayrıca, elde edilen bulgulara dayanılarak elektro-indirgenme reaksiyonunun yürüyüşü için bir mekanizma önerilmiştir.

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Cite This Article

PEKEL, A. T., POLAT, K. (2022). The organic solvent and acid effect on the electro-reduction reaction of the 4-nitroso-N,N-dimetilaniline on graphite electrode. Anadolu Üniversitesi Bilim ve Teknoloji Dergisi :A-Uygulamalı Bilimler ve Mühendislik, Cilt: 7 - Sayı: 1, 195–204. https://ajindex.com/articles/438399

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