Journals / Anadolu Üniversitesi Bilim ve Teknoloji Dergisi :A-Uygulamalı Bilimler ve Mühendislik / 2016 / Cilt: 17 - Sayı: 4

ADSORPTION KINETICS OF Cd2+ IONS ONTO MgPz THIN FILM

Pages
622–632
Publication Date
2022-10-11
DOI
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The quartz crystal microbalance results indicated that the MgPz coated sensor exhibited high sensitivity, stability and selectivity for the detection of Cd in aqueous solution.

📌 3 Key Takeaways

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Objective & Hypothesis:A (2,3,7,8,12,13,17,18-Octakis(4-tert-butylbenzylthio)-porphyrazinato)Mg(II) functionalized quartz crystal microbalance sensor has been developed for the detection of trace Cd2+ions in water samples.
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Key Findings & Data:The lowest detection limit can reach 10 ?g/ml Cd2+ in aqueous solution, which resulted in the frequency shift of ? 150 Hz.
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Conclusion & Impact:The quartz crystal microbalance results indicated that the MgPz coated sensor exhibited high sensitivity, stability and selectivity for the detection of Cd in aqueous solution.
🔬Design:Modeling & Simulation
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

A (2,3,7,8,12,13,17,18-Octakis(4-tert-butylbenzylthio)-porphyrazinato)Mg(II) functionalized quartz crystal microbalance sensor has been developed for the detection of trace Cd2+ions in water samples. The quartz crystal microbalance results indicated that the MgPz coated sensor exhibited high sensitivity, stability and selectivity for the detection of Cd in aqueous solution. The lowest detection limit can reach 10 ?g/ml Cd2+ in aqueous solution, which resulted in the frequency shift of ? 150 Hz. The observed adsorption data were analyzed using four adsorption kinetic models; the Elovich equation, Ritchie's equation, pseudo first- and second-order equations. Results show that the linear regression analysis with respect to pseudosecond-order rate equation generates a straight line that best fit to the data of adsorption of Cd2+ on Pz film.

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Cite This Article

ALTINDAL, A., ÖMÜR, B. C., CAN, N. (2022). ADSORPTION KINETICS OF Cd2+ IONS ONTO MgPz THIN FILM. Anadolu Üniversitesi Bilim ve Teknoloji Dergisi :A-Uygulamalı Bilimler ve Mühendislik, Cilt: 17 - Sayı: 4, 622–632. https://ajindex.com/articles/438342

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References (13)

  1. Gumpu MB, Sethuraman S, Krishnan UM, Rayappan JBB. A review on detection of heavy metal ions in water - An electrochemical approach. Sensor Actuat B-Chem 2015; 213: 515-533.
  2. Cherian S, Gupta RK, Mullin BC, Thundat T. Detection of heavy metal ions using protein- functionalized microcantilever sensors. Biosens Bioelectron 2003; 19: 411-416.
  3. Kadirvelu K, Namasivayam C. Agricultural by-products as metal adsorbents: Sorption of lead (II) from aqueous solutions onto coirpith carbon. Environ Technol 2000; 21: 1091-1097.
  4. Cao Z, Guo J, Fan X, Xu J, Fan Z, Du B. Detection of heavy metal ions in aqueous solution by P(MBTVBC-co-VIM)-coated QCM sensor. Sensor Actuat B-Chem 2011; 157: 34-41.
  5. Dekhil AB, Hannachi Y, Ghorbel A, Boubaker T. Removal of Lead and Cadmium Ions From Aqueous Solutions Using Dried Marine Green Macroalga (Caulerpa racemosa). Int J Environ Res 2011; (3): 725-732.
  6. Hamilton MA, Rode PW, Merchant ME, Sneddon J. Determination and comparison of heavy metals in selected seafood, water, vegetation and sediments by inductively coupled plasma-optical emission spectrometry from an industrialized and pristine waterway in Southwest Louisiana. Microchem J 2008;: 52-55.
  7. Bibby A, Mercier L. Mercury (II) ion adsorption behavior in thiol-functionalized mesoporous silica microspheres. Chem Mater 2002; 14: 1579-1591.
  8. Fanata K, Chandravanshi BS. Differential pulse anodic stripping voltammetric determination of cadmium(II) with N-p-chlorophenylcinnamohydroxamic acid modified carbon paste electrode. Electroanalysis 2001; 13: 484-492.
  9. Abdunasser ME, Hillman AR, Ryder KS, Glidle A. Quartz crystal microbalance determination of trace metal ions in solution. J Electroanal Chem 2007; 599: 275-287.
  10. Ju JF, Syu MJ, Teng HS, Chou SK, Chang YS. Preparation and identification of ?- cyclodextrin polymer thin film for quartz crystal microbalance sensing of benzene, toluene, and p-xylene. Sensor Actuat B-Chem 2008; 132: 319-326.
  11. Xu Z, Kang Q, Cai T, Huang T, Zhang P, Shen D. A quartz crystal microbalance study of the adsorption kinetics of 1,2-dichloroethane on metal organic frameworks [Cu(C24H22N4O3)]·CH2Cl2 film. Thin Solid Films 2014; 556: 325-332.
  12. Kolev I, Mavrodinova V, Alexieva G, Strashilov V. Pore volume probing of boron modified MCM- zeolite by quartz crystal microbalance assisted study of o- and p-xylene adsorption. Sensor Actuat B-Chem 2010; 149: 389-394.
  13. Ceyhan T, Altındal A, Özkaya AR, Erbil MK, Bekaroğlu Ö. Synthesis, characterization, and electrochemical, electrical and