Journals / Anadolu Üniversitesi Bilim ve Teknoloji Dergisi :A-Uygulamalı Bilimler ve Mühendislik / 2017 / Cilt: 18 - Sayı: 3

BIOSYNTHESIS, CHARACTERISATION AND DETERMINATION OF ADSORBENT PROPERTIES OF SILVER NANOPARTICLES WITH CYPRUS ACACIA (Acacia cyanophylla) LEAF EXTRACT

Pages
733–745
Publication Date
2022-10-11
DOI
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⚡ TL;DR(Too Long; Didn't Read)

From Weber-Morris model, it was concluded that only intraparticle mass transfer was effective on the adsorption of BR 46 by AgNPs.

📌 3 Key Takeaways

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Objective & Hypothesis:In this work, silver nanoparticles (AgNPs) were biosynthesized using Cyprus acacia (Acacia cyanophylla) leaf extract as reductant agent; the biosynthesized AgNPs were characterized by DLS, FT-IR, SEM, EDX, and XRD.
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Key Findings & Data:Then, the single and multistage batch adsorption of Basic Red 46 dye (BR46) onto AgNPs were studied and the optimum conditions were determined as follows: initial pH of 7.0, initial dye concentration of 200 mg/L, temperature of 35 oC, and adsorbent concentration of 1.0 g/L.
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Conclusion & Impact:From Weber-Morris model, it was concluded that only intraparticle mass transfer was effective on the adsorption of BR 46 by AgNPs.
🔬Design:Modeling & Simulation
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

In this work, silver nanoparticles (AgNPs) were biosynthesized using Cyprus acacia (Acacia cyanophylla) leaf extract as reductant agent; the biosynthesized AgNPs were characterized by DLS, FT-IR, SEM, EDX, and XRD. Then, the single and multistage batch adsorption of Basic Red 46 dye (BR46) onto AgNPs were studied and the optimum conditions were determined as follows: initial pH of 7.0, initial dye concentration of 200 mg/L, temperature of 35 oC, and adsorbent concentration of 1.0 g/L. For BR 46-AgNPs adsorption, the equilibrium was defined by Langmuir isotherm model and the adsorption kinetic data were best described by the pseudo second order kinetic model. From Weber-Morris model, it was concluded that only intraparticle mass transfer was effective on the adsorption of BR 46 by AgNPs. It was obtained from the thermodynamic studies that the studied adsorption system was exothermic, induced, and decreasing in randomness of adsorbed species.

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Cite This Article

UZUNOĞLU, D., ÖZER, A., TAŞKIRAN, F. (2022). BIOSYNTHESIS, CHARACTERISATION AND DETERMINATION OF ADSORBENT PROPERTIES OF SILVER NANOPARTICLES WITH CYPRUS ACACIA (Acacia cyanophylla) LEAF EXTRACT. Anadolu Üniversitesi Bilim ve Teknoloji Dergisi :A-Uygulamalı Bilimler ve Mühendislik, Cilt: 18 - Sayı: 3, 733–745. https://ajindex.com/articles/438299

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References (12)

  1. Ghaedi M, Sadeghian B, Pebdani AA, Sahraei R, Daneshfar A and Duran C. Kinetics, thermodynamics and equilibrium evaluation of direct yellow 12 removal by adsorption onto silver nanoparticles loaded activated carbon. Chem Eng J 2012; 187: 133-141
  2. Haiss W, Thanh NT, Aveyard J and Fernig DG. Determination of size and concentration of gold nanoparticles from UV-vis spectra. Anal Chem 2007; 79(11): 4215-4221
  3. Umer A, Naveed S, Ramzan N and Rafique MS. Selection of a suitable method for the synthesis of copper nanoparticles. Nano 2012; 7(05): 1230005
  4. Veerasamy R, Xin TZ, Gunasagaran S, Xiang TFW, Yang EFC. Jeyakumar N and Dhanaraj SA. Biosynthesis of silver nanoparticles using mangosteen leaf extract and evaluation of their antimicrobial activities. J Saudi Chem Soc 2011; 15(2): 113-120
  5. Awwad AM, Salem NM, and Abdeen AO. Green synthesis of silver nanoparticles using carob leaf extract and its antibacterial activity. IJIC 2013; 4(1): 1-6
  6. Muthukumaran U, Govindarajan M, Rajeswary M and Hoti SL. Synthesis and characterization of silver nanoparticles using Gmelina asiatica leaf extract against filariasis, dengue, and malaria vector mosquitoes. Parasitol Res 2015; 114(5): 1817-1827
  7. Mishra PM, Sahoo SK, Naik GK and Parida K. Biomimetic synthesis, characterization and mechanism of formation of stable silver nanoparticles using Averrhoa carambola L. leaf extract. Mater Lett 2015; 160: 566-571
  8. Sathyavathi R, Krishna MB, Rao SV, Saritha R and Rao DN. Biosynthesis of silver nanoparticles using Coriandrum sativum leaf extract and their application in nonlinear optics. Adv Sci Lett 2010; 3(2): 138-143
  9. Aitenneite H, Abboud Y, Tanane O, Solhy A, Sebti S and Bouari AE. Rapid and green microwaveassisted synthesis of silver nanoparticles using aqueous Phoenix Dactylifera L. (date palm) leaf extract and their catalytic activity for 4-Nitrophenol reduction. J Mater Environ Sci 2016; 7(7): 2335-2339
  10. Kumar DA, Palanichamy V and Roopan SM. Green synthesis of silver nanoparticles using Alternanthera dentata leaf extract at room temperature and their antimicrobial activity. Spectrochim Acta A Mol Biomol Spectrosc 2014; 127: 168-171
  11. Prakash P, Gnanaprakasam P, Emmanuel R, Arokiyaraj S and Saravanan M. Green synthesis of silver nanoparticles from leaf extract of Mimusops elengi, Linn. for enhanced antibacterial activity against multi drug resistant clinical isolates. Colloids Surf B Biointerfaces 2013; 108: 255-259
  12. Khalil MM, Is