Journals / Anadolu Üniversitesi Bilim ve Teknoloji Dergisi :A-Uygulamalı Bilimler ve Mühendislik / 2018 / Cilt: 19 - Sayı: 2

EVALUATION OF ANAEROBICALLY DIGESTED BIOMASS IN CATALYTIC SUPERCRITICAL WATER GASIFICATION FOR BIOFUEL PRODUCTION

Pages
407–421
Publication Date
2022-10-11
DOI
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⚡ TL;DR(Too Long; Didn't Read)

High organic content of digested biomass was converted by supercritical water gasification to methaneand hydrogen rich gas, and aqueous products (aliphatic hydrocarbons, phenol, substituted phenols, N-heterocyclic,substituted N-heterocyclics, and substituted benzene) that can be evaluated as platform chemicals.

📌 3 Key Takeaways

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Objective & Hypothesis:Digested water hyacinth with waste sludge as inoculum were obtained after anaerobic digestion at 35 and 45°C.
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Key Findings & Data:High organiccontent of digested biomass were evaluated through gasification at supercritical conditions of water in the absence andpresence of catalysts (KOH, NaOH, LiOH and K2CO3) with 10 wt.% of volatile solid in feed.
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Conclusion & Impact:High organic content of digested biomass was converted by supercritical water gasification to methaneand hydrogen rich gas, and aqueous products (aliphatic hydrocarbons, phenol, substituted phenols, N-heterocyclic,substituted N-heterocyclics, and substituted benzene) that can be evaluated as platform chemicals.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

Digested water hyacinth with waste sludge as inoculum were obtained after anaerobic digestion at 35 and 45°C. High organiccontent of digested biomass were evaluated through gasification at supercritical conditions of water in the absence andpresence of catalysts (KOH, NaOH, LiOH and K2CO3) with 10 wt.% of volatile solid in feed. Supercritical water gasificationof digested biomass was performed in batch reactor system at temperature and pressure ranges of 500–600°C and 35–45MPa, respectively. The highest carbon gasification efficiency, hydrogen and methane yields were reached at 600°C (withsamples digested at 45°C) in the absence of catalyst as 84.6 (g C in gaseous/g C in digestate), 53.0 (mol $H2%$) and 14.2 (mol$CH4%$), respectively. High organic content of digested biomass was converted by supercritical water gasification to methaneand hydrogen rich gas, and aqueous products (aliphatic hydrocarbons, phenol, substituted phenols, N-heterocyclic,substituted N-heterocyclics, and substituted benzene) that can be evaluated as platform chemicals.

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Cite This Article

MADENOĞLU, T. G. (2022). EVALUATION OF ANAEROBICALLY DIGESTED BIOMASS IN CATALYTIC SUPERCRITICAL WATER GASIFICATION FOR BIOFUEL PRODUCTION. Anadolu Üniversitesi Bilim ve Teknoloji Dergisi :A-Uygulamalı Bilimler ve Mühendislik, Cilt: 19 - Sayı: 2, 407–421. https://ajindex.com/articles/438230

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References (13)

  1. Möller K, Müller T. Effects of anaerobic digestion on digestate nutrient availability and crop growth: a review. Eng Life Sci 2012; 12: 242–257
  2. Scano EA, Asquer C, Pistis A, Ortu L, Demontis V, Cocco D. Biogas from anaerobic digestion of fruit and vegetable wastes: Experimental results on pilot-scale and preliminary performance evaluation of a full-scale power plant. Energ Convers Manage 2014; 77: 22–30
  3. Alburquerque JA, Fuente C, Ferrer-Costa A, Carrasco L, Cegarra J, Abad M, Bernal MP. Assessment of the fertiliser potential of digestates from farm and agroindustrial residues. Biomass Bioenerg 2012; 40: 181–189
  4. Wang H, Miao R, Yang Y, Qiao Y, Zhang Q, Li C, Huang J. Study on the catalytic gasification of alkali lignin over Ru/C nanotubes in supercritical water. J Fuel Chem Technol 2015; 43: 1195– 1201
  5. Pooya A, Sami K, Friederike S, Faraz A, Ramin F. Hydrogen production from cellulose, lignin, bark and model carbohydrates in supercritical water using nickel and ruthenium catalysts. Appl Catal B-Environ 2012; 117–118: 330–338
  6. Ning D, Ramin A, Ajay KD, Janusz AK. Catalytic gasification of cellulose and pinewood to H2 in supercritical water. Fuel 2014; 118: 416–425
  7. Weijin G, Binbin L, Qingyu W, Zuohua H, Liang Z. Supercritical water gasification of landfill leachate for hydrogen production in the presence and absence of alkali catalyst. Waste Manage 2017; In Press, Corrected Proof, Available online 18 December 2017 (
  8. Sheikhdavoodi MJ, Almassi M, Ebrahimi-Nik M, Kruse A, Bahrami H. Gasification of sugarcane bagasse in supercritical water; evaluation of alkali catalysts for maximum hydrogen production. J Energy Inst 2015; 88: 450–458
  9. Aaron KG, Gregory LR. Reaction rates for supercritical water gasification of xylose in a microtubular reactor. Chem Eng J 2010; 163: 10–21
  10. Nanda S, Reddy SN, Hunter HN, Dalai AK, Kozinski JA. Supercritical water gasification of fructose as a model compound for waste fruits and vegetables. J Supercrit Fluid 2015; 104: 112– 121
  11. Watanabe M, Inomata H, Osada M, Sato T, Adschiri T, Arai K. Catalytic effects of NaOH and ZrO2 for partial oxidative gasification of n-hexadecane and lignin in supercritical water. Fuel 2003; 82: 545–552
  12. Yoshida T, Matsumura Y. Gasification of cellulose, xylan, and lignin mixtures in supercritical water. Ind Eng Chem Res 2001; 40: 5469–5474
  13. Kruse A, Meier D, Rimbrecht P, Schacht M. Gasification of py