Journals / Anadolu Üniversitesi Bilim ve Teknoloji Dergisi :A-Uygulamalı Bilimler ve Mühendislik / 2018 / Cilt: 19 - Sayı: 1

EFFECT OF N DOPING ON TL2GA2S3SE SINGLE CRYSTALS: THERMOLUMINESCENCE CHARACTERIZATION OF DEFECT CENTERS

Pages
24–31
Publication Date
2022-10-11
DOI
—
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AI Summary & Key Takeaways

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⚡ TL;DR(Too Long; Didn't Read)

The effect ofthe N doping on the existed defects was discussed.

📌 3 Key Takeaways

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Objective & Hypothesis:Thermoluminescence study on nitrogen doped Tl2Ga2S3Se single crystals was achieved by performing the experiments withdifferent stopping temperatures of 10−24 K and various heating rates between 0.4 and 1.2 K/s below room temperature.Thermoluminescence peak with peak maximum temperature of 54 K was detected from the emitted luminescence.
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Key Findings & Data:Curve fitting and initial rise methods were applied to compute the activationenergies and the values of 34 ± 2 and 70 ± 4 meV were found.
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Conclusion & Impact:The effect ofthe N doping on the existed defects was discussed.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

Thermoluminescence study on nitrogen doped Tl2Ga2S3Se single crystals was achieved by performing the experiments withdifferent stopping temperatures of 10−24 K and various heating rates between 0.4 and 1.2 K/s below room temperature.Thermoluminescence peak with peak maximum temperature of 54 K was detected from the emitted luminescence. Two traplevels were obtained from the observed spectra. Curve fitting and initial rise methods were applied to compute the activationenergies and the values of 34 ± 2 and 70 ± 4 meV were found. Thermal cleaning process was applied to separate the overlappingpeaks and so true energy region of trapping levels was corroborated. Moreover, variations of shape and position of TL curvewere studied by investigating the heating rate behavior of trap levels. The best known behavior which the peak maximumtemperature increases while the thermoluminescence intensity decreases with raising heating rate was observed. The effect ofthe N doping on the existed defects was discussed.

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Cite This Article

DELİCE, S. (2022). EFFECT OF N DOPING ON TL2GA2S3SE SINGLE CRYSTALS: THERMOLUMINESCENCE CHARACTERIZATION OF DEFECT CENTERS. Anadolu Üniversitesi Bilim ve Teknoloji Dergisi :A-Uygulamalı Bilimler ve Mühendislik, Cilt: 19 - Sayı: 1, 24–31. https://ajindex.com/articles/438227

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References (11)

  1. Anishia SR, Jose MT, Annalakshmi O, Ramasamy V. Thermoluminescence properties of rare earth doped lithium magnesium borate phosphors. J Lumin 2011; 131: 2492-2498.
  2. Chen R, McKeever SWS. Theory of Thermoluminescence and Related Phenomena. Singapore: World Scientific, 1997.
  3. Chen R, Kirsh Y. Analysis of Thermally Stimulated Processes. Oxford, New York, USA: Pergamon Press, 1981.
  4. Delice S, Isik M, Bulur E, Gasanly NM. Thermoluminescence properties of Tl2Ga2S3Se layered single crystals. J Appl Phys 2013; 113: 193510:1-193510:5. Yildirim T, Gasanly NM. Determination of deep trapping center parameters in as-grown Tl2Ga2S3Se layered crystals. Solid State Sci 2009; 11: 1562-1566.
  5. Yildirim T, Nasser HA, Gasanly NM. Determination of trapping center parameters of Tl2Ga2S3Se layered crystals by thermally stimulated current measurements. Int J Mod Phys B 2010; 24: 2149- 2161. Gasanly NM. Low-temperature absorption edge and photoluminescence in layered structured Tl2Ga2S3Se single crystals. Physica B 2012; 407: 4318-4322.
  6. Isik M, Gasanly NM. Absorption edge and optical constants of Tl2Ga2S3Se crystals from reflection and transmission, and ellipsometric measurements. Physica B 2012; 407: 2229-2233.
  7. Muller D, Hahn H. Ternary chalcogenides 24. structure of TlGaSe2. Z Anorg Allg Chem 1978; 438: 258-272.
  8. Yee KA, Albright A. Bonding and structure of TlGaSe2. J Am Chem Soc 1991; 113: 6474-6478.
  9. Allakhverdiev KR, Mamedov TG, Akinoglu BG, Ellialtioglu S. Phase transitions in ternary layered A3B3C2 6 group ferroelectric semiconductors—A Review. Turk J Phys 1994; 18: 1-66. Panich AM. Electronic properties and phase transitions in low-dimensional semiconductors. J Phys-Condens Mat 2008; 20: 293202:1-293202:42. Guler I, Gasanly NM. Optical properties of TlGaSeS layered single crystals. J Korean Phys Soc 2007; 51: 2031-2035. Allakhverdiev KR. Two-photon absorption in layered TlGaSe2, TlInS2, TlGaS2 and GaSe crystals. Solid State Commun 1999; 111: 253-257.
  10. Gurbulak B, Duman S. Urbach tail and optical characterization of gadolinium-doped TlGaSe2 single crystals. Phys Scripta 2008; 77: 025702:1-025702:6. Grivickas V, Bikbajevas V, Grivickas P. Indirect absorption edge of TlGaSe2 crystals. Phys Status Solidi B 2006; 243: R31-R33. El Nahass MM, Sallam MM, Rahman SA, Ibrahim EM. Optical, electrical conduction and dielectric properties of TlGaSe2 layered single crystal. Solid State Sci 2006; 8: 488-499.
  11. Kato A, Nishigaki M, Mamedov N, Yamazaki M, Abdullaeva S, Kerimova E, Uchiki H, Iida S. O