Journals / Sigma Mühendislik ve Fen Bilimleri Dergisi / 2014 / Cilt: 32 - Sayı: 1

PREPARATION OF POLY(METHYL METHACRYLATE)/CLAY NANOCOMPOSITES AND INVESTIGATION OF SOME PHYSICAL PROPERTIES

Pages
71–80
Publication Date
2014-03-01
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The optical properties were obtained by measuring transmittance values in a UV-VIS spectrophotometer.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:In the present study, the synthesis, characterization, thermal and optical properties of poly(methyl methacrylate)(PMMA)/organomodified montmorillonit clay (OMTAB) nanocomposites were investigated.
📊
Key Findings & Data:PMMA/nanoclay composites were synthesized by in situ polymerization method.
💡
Conclusion & Impact:The optical properties were obtained by measuring transmittance values in a UV-VIS spectrophotometer.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Polymer/clay nanocomposites · exfoliation/intercalation · thermal degradation kinetics

Abstract

In the present study, the synthesis, characterization, thermal and optical properties of poly(methyl methacrylate)(PMMA)/organomodified montmorillonit clay (OMTAB) nanocomposites were investigated. PMMA/nanoclay composites were synthesized by in situ polymerization method. Organomodified montmorillonit clay and PMMA/OMTAB nanocomposites were characterized by FTIR technique. The interlayer spacing of the organoclay platelets and the polymer clay nanocomposites were determined by X-ray diffraction spectroscopy. It was determined that the clay dispersion in the polymer matrix was exfoliated behavior. Thermal behaviors and thermal degradation activation energies of nanocomposites were determined by thermogravimetric analysis method (TGA). Polymer/nanocomposite thin films on the quartz surface were prepared by spin coating technique. The optical properties were obtained by measuring transmittance values in a UV-VIS spectrophotometer.

🔖

Cite This Article

KURT, A., ÇAĞLAYAN, Z., BEKTAŞ, H. S. (2014). PREPARATION OF POLY(METHYL METHACRYLATE)/CLAY NANOCOMPOSITES AND INVESTIGATION OF SOME PHYSICAL PROPERTIES. Sigma Mühendislik ve Fen Bilimleri Dergisi, Cilt: 32 - Sayı: 1, 71–80. https://ajindex.com/articles/419378

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (14)

  1. Park J.H., Jana S.C., “The relationship between nano- and micro-structures and mechanical properties in PMMA-epoxy-nanoclay composites”, Polymer, 44, 2091-2100, 2003
  2. Powell C.E., Beall G.W., “Physical properties of polymer/clay nanocomposites”, Solid State and Materials Science 10, 73–80, 2006
  3. Utracki L.A., Sepehr M., Boccaleri E., “Synthetic, layered nanoparticles for polymeric nanocomposites (PNCs)”, Polymers for Advanced Technologies, 18, 1-37, 2007
  4. Wang W.S., Liang C.K., Chen Y.C., et al., “Transparent and flame retardant PMMA/clay nanocomposites prepared with dual modified organoclay”, Polymers for Advanced Technologies, 23, 625-631, 2012
  5. Hu Y.H., Chen C.Y., Wang C.C., “Viscoelastic properties and thermal degradation kinetics of silica/PMMA nanocomposites”, Polymer Degradation and Stability, 84, 545-553, 2004
  6. Lerari D., Peeterbroeck S., Benali S., et al., “Combining atomtransfer radical polymerization and melt compounding for producing PMMA/clay nanocomposites”, Journal of Applied Polymer Science, 121, 1355-1364, 2011
  7. Lee M.H., Dan C.H., et al., “Effect of clay on the morphology and properties of PMMA/poly(styrene-co-acrylonitrile)/clay nanocomposites prepared by melt mixing”, Polymer, 47, 4359-4369, 2006
  8. Haraguchi K., “Nanocomposite hydrogels”, Current Opinion in Solid State and Materials Science, 11, 47–54, 2007
  9. Powell C.E., Beall G.W., “Physical properties of poly- mer/clay nanocomposites”, Current Opinion in Solid State and Materials Science, 10, 73–80, 2006
  10. Wang Y., Chen W.C., “Dielectric Probing of Relaxation Behaviors in PMMA/Organoclay Nanocomposites: Effect of Organic Modification”, Composite Interfaces, 17, 803-829, 2010
  11. Zeng C., Lee L.J., “Poly(methyl methacrylate) and Polystyrene/Clay nanocomposites prepared by in-situ polymerization”, Macromolecules, 34, 4098-4013, 2001
  12. Zhang W.A., Chen D.Z., et al., “Influence of four different types of organophilic clay on the morphology and thermal properties of polystyrene/clay nanocomposites prepared by using the γ-ray irradiation technique”, European Polymer Journal, 39, 2323–2328, 2003
  13. Madurai S.L., Joseph S.W., et al., “Intestine-specific, oral delivery of captopril/montmorillonite: formulation and release kinetics”, Nanoscale Research Letters, 6:15, 2011
  14. Fan X., Xia C., Advincula R.C., “Intercalation of polymerization initiators into montmorillonite nanoparticle platelets: free radical vs. anionic initiator clays”, Colloids