From thermal analysis, a positive correlation was observed between the clay ratio and thermal stability of nanomaterials.
📌 3 Key Takeaways
🎯
Objective & Hypothesis:In this study, the synthesis, characterization, and thermal properties of poly(2-(4-methoxyphenyl amino)-2-oxoethyl methacrylate) (MPAEMA) polymer/clay based nanocomposites were investigated by in situ polymerization.
📊
Key Findings & Data:It was determined from XRD and SEM measurements that the morphology of nanocomposites was exfoliated when the clay content in the polymer matrix was kept at 3% and 5%.
💡
Conclusion & Impact:From thermal analysis, a positive correlation was observed between the clay ratio and thermal stability of nanomaterials.
In this study, the synthesis, characterization, and thermal properties of poly(2-(4-methoxyphenyl amino)-2-oxoethyl methacrylate) (MPAEMA) polymer/clay based nanocomposites were investigated by in situ polymerization. At the characterizations of nanomaterials FTIR, XRD, SEM, and TGA techniques were used. It was determined from XRD and SEM measurements that the morphology of nanocomposites was exfoliated when the clay content in the polymer matrix was kept at 3% and 5%. From thermal analysis, a positive correlation was observed between the clay ratio and thermal stability of nanomaterials.
Mandalia, T., Bergaya, F., (2006) Organo clay mineral-melted polyolefin nanocomposites effect of surfactant/CEC Ratio, Journal of Physics and Chemistry of Solids, 67, 836-845
İşçi, S., Ece, Ö.I., Güngör, N., (2006) Characterization of rheology, electrokinetic properties and surface micromorphology of DTABr/MMT and CPBr/MMT organoclays, Journal of Composite Materials, 40, 1105-1115
Mandalia, T., Bergaya, F., (2006) Organo clay mineral-melted polyolefin nanocomposites effect of surfactant/CEC Ratio, Journal of Physics and Chemistry of Solids, 67, 836-845
Ray, S.S., Okamoto, M., (2003) Polymer/Layered Silicate Nanocomposites: A Review from Preparation to Processing, Progress in Polymer Science, 28, 1539-1641
Çankaya, N., Besci, G., (2018) Synthesis, characterization, thermal properties and reactivity ratios of methacrylate copolymers including methoxy group, Journal of the Faculty of Engineering and Architecture of Gazi University, 33(3), 1155-1170
Daşbaşı, T., Soykan, C., Çankaya, N., Ülgen, A., (2018) Determination of some trace metals with a new synthesized polymer resin by FAAS in various tea and herbal plants samples, Journal of Macromolecular Science, Part A: Pure and Applied Chemistry, 55(6), 466-473
Çankaya, N., (2020) Preparaiıon of Oxo Methacrylate-Containing Polymer/Clay Based Nanocomposites, International Transaction Journal of Engineering, Management,&Applied Sciences&Technologies, 128, 11(7), 1-8
Zhang, W.A., Chen, D.Z., Xu, H.Y., Shen, X.F., Fang Y.E., (2003) Influence of four different types of organophilic clay on the morphology and thermal properties of polystyrene/clay nanocomposites prepared by using the c-ray irradiation technique, European Polymer Journal, 39(12), 2323-2328
Kurt, A., Topsoy, O.K., (2017) Preparation of Novel Coumarin Cyclic Polymer/Montmorillonite Based Nanocomposites, Russian Journal of Applied Chemistry, 90(12), 2019−2027
Delibas, A., Alparslan, M., (2015) Synthesis and characterization of halogen-containing aryl amide polymer-clay nanocomposites, Turkish Journal of Chemistry, 39, 630-638