Journals / Sinop Üniversitesi Fen Bilimleri Dergisi / 2016 / Cilt: 1 - Sayı: 1

Dimethyl sulfoxide Species Entrapped by Raw and Acid-Activated Sepiolite Framework

Pages
76–82
Publication Date
2016-08-09
DOI
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The data presented in this study may also provide further insight into catalysis studies and the application of clays in the growing field of environmental management.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:Novel hybrid organic-clay materials were prepared by interaction of dimethyl sulfoxide molecules in the interlayer space of raw and acid activated sepiolite composites.
📊
Key Findings & Data:The noticeable surface area increase of activated sepiolite than that of the raw one is connected to the micropore formation.
💡
Conclusion & Impact:The data presented in this study may also provide further insight into catalysis studies and the application of clays in the growing field of environmental management.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:dimethyl sulfoxide · sepiolite · interstitial water

Özet

Novel hybrid organic-clay materials were prepared by interaction of dimethyl sulfoxide molecules in the interlayer space of raw and acid activated sepiolite composites. The structural and thermal properties of the hybrid materials, raw and acid activated sepiolite were examined by using Fourier transform infrared, thermal analysis, X-ray powder diffraction and surface area measurement techniques. Thermal analysis data prove the remarkable effects of acid activation on the framework of sepiolite which are reflected by the intercalation mechanism proceeding through the replacement partly of the interstitial water by dimethyl sulfoxide species. The protons are directly involved in the actual structure and thus enhances the thermal stability of the complex between dimethyl sulfoxide and the sepiolite. The noticeable surface area increase of activated sepiolite than that of the raw one is connected to the micropore formation. The data presented in this study may also provide further insight into catalysis studies and the application of clays in the growing field of environmental management.

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Cite This Article

Tabak, A., Afşin, B., Çağlar, B., Çağlar, S. (2016). Dimethyl sulfoxide Species Entrapped by Raw and Acid-Activated Sepiolite Framework. Sinop Üniversitesi Fen Bilimleri Dergisi, Cilt: 1 - Sayı: 1, 76–82. https://ajindex.com/articles/415104

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References (14)

  1. Zhou Q, Frost R L, He H, Xi Y, 2007. Changes in the surfaces of adsorbed para-nitrophenol on HDTMA organoclay-The XRD and TG study, J. Colloid Interface Sci., 307 (1): 50-55
  2. Hrachová J, Madejová J, Billik P, Komadel P, Fajnor VŠ, 2007. Dry grinding of Ca- and octadecyltrimethylammonium montmorillonite, J. Colloid Interface Sci., 316: 589-595
  3. Liu B, Wang X, Yang B, Sun R, 2011. Rapid modification of montmorillonite with novel cationic gemini surfactants and its adsorption for methylorange, Mater. Chem. Phys., 130: 1220-1226
  4. Karagüzel C, Çetinel T, Boylu F, Çinku K, Çelik M S, 2010. Activation of (Na, Ca)-Bentonites with Soda and MgO and their utilization as Drilling Mud, Appl. Clay Sci., 48: 398-404
  5. Karakaya M Ç, Karakaya N, Bakır S, 2011. Some Properties and Potential Applications of the Na- And Ca-Bentonites of Ordu (N.E. Turkey), Appl. Clay Sci., 54: 159-165
  6. Hu Z, He G, Liu Y, Dong C, Wu X, Zhao W, 2013. Effects of surfactant concentration on alkyl chain arrangements in dry and swollen organic montmorillonite, Appl. Clay Sci., 75-76: 134-140
  7. Noyan H, Önal M, Sarıkaya Y, 2007. The effect of sulphuric acid activation on the crystallinity, surface area, porosity, surface acidity, and bleaching power of a bentonite, Food Chem., 105: 156-163
  8. Lagaly G, 1986. Interaction of alkylamines with different types of layered compounds, Solid State Ionics, 22(1) 43-51
  9. Yariv S, Lapides I, Nasser A, Lahav N, Brodsky I, Michaelian K H, 2000. Infrared study of the intercalation of potassium halides in kaolinite, Clays Clay Miner., 48(1): 10-18
  10. Noyan H, Önal M, Sarikaya Y, 2006. The effect of heating on the surface area, porosity and surface acidity of a bentonite, Clays Clay Miner., 54: 375-381
  11. Tabak A, Afsin B, Caglar B, Koksal E, 2007. Characterization and pillaring of a Turkish bentonite (Resadiye), J. Colloid Interface Sci., 313(1): 5-11
  12. He H, Ma Y, Zhu J, Yuan P, Qing Y, 2010. Organoclays prepared from montmorillonites with different cation exchange capacity and surfactant configuration, Appl. Clay Sci., 48(1-2): 67-72
  13. Zu R, Wang T, Zhu J, Ge F, Yuan P, He H, 2010. Structural and sorptive characteristics of the cetyltrimethylammonium and polyacrylamide modified bentonite, Chem. Eng. J., 160(1): 220-225
  14. Zhu J, Qing Y, Wang T, Zhu R, Wei J, Tao Q, Yuan P, He H, 2011. Preparation and characterization of zwitterionic surfactant-modified montmorillonites, J. Colloid Interface Sci., 360(2): 386-392. [1